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Article: Complex formation between bisparaphenylene-(3n + 4)-crown-n ethers and the Paraquat and Diquat dications

TitleComplex formation between bisparaphenylene-(3n + 4)-crown-n ethers and the Paraquat and Diquat dications
Authors
Ashton, Peter R.Slawin, Alexandra M.Z.Spencer, NeilStoddart, J. FraserWilliams, David J.
Issue Date1987
Citation
Journal of the Chemical Society, Chemical Communications, 1987, n. 14, p. 1066-1069 How to Cite?
DOI: http://dx.doi.org/10.1039/C39870001066
AbstractU.v. and n.m.r. spectroscopic investigations in solution have been employed to assess the ability of a series (n = 7-12) of bisparaphenylene-(3n + 4)-crown-n ethers to form stable 1:1 complexes with [Diquat]2+ and [Paraquat]2+ dications; these mappings of molecular recognition are supported by fast atom bombardment mass spectrometry of the 1:1 complexes with both [Diquat][PF6]2 and [Paraquat][PF6] 2, and a single crystal X-ray structure analysis of [Diquat·BPP31C9][PF6]2.
Persistent Identifierhttp://hdl.handle.net/10722/332768
ISSN
0022-4936
ISI Accession Number ID
WOS:A1987J524400009

 

DC FieldValueLanguage
dc.contributor.authorAshton, Peter R.-
dc.contributor.authorSlawin, Alexandra M.Z.-
dc.contributor.authorSpencer, Neil-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorWilliams, David J.-
dc.date.accessioned2023-10-06T05:14:07Z-
dc.date.available2023-10-06T05:14:07Z-
dc.date.issued1987-
dc.identifier.citationJournal of the Chemical Society, Chemical Communications, 1987, n. 14, p. 1066-1069-
dc.identifier.issn0022-4936-
dc.identifier.urihttp://hdl.handle.net/10722/332768-
dc.description.abstractU.v. and n.m.r. spectroscopic investigations in solution have been employed to assess the ability of a series (n = 7-12) of bisparaphenylene-(3n + 4)-crown-n ethers to form stable 1:1 complexes with [Diquat]2+ and [Paraquat]2+ dications; these mappings of molecular recognition are supported by fast atom bombardment mass spectrometry of the 1:1 complexes with both [Diquat][PF6]2 and [Paraquat][PF6] 2, and a single crystal X-ray structure analysis of [Diquat·BPP31C9][PF6]2.-
dc.languageeng-
dc.relation.ispartofJournal of the Chemical Society, Chemical Communications-
dc.titleComplex formation between bisparaphenylene-(3n + 4)-crown-n ethers and the Paraquat and Diquat dications-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/C39870001066-
dc.identifier.scopuseid_2-s2.0-37049080225-
dc.identifier.issue14-
dc.identifier.spage1066-
dc.identifier.epage1069-
dc.identifier.isiWOS:A1987J524400009-

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