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Article: Blue-colored donor-acceptor [2]rotaxane

TitleBlue-colored donor-acceptor [2]rotaxane
Authors
Issue Date2007
Citation
Organic Letters, 2007, v. 9, n. 8, p. 1481-1484 How to Cite?
AbstractEquation presented A guest molecule - a bis-N-tetraethyleneglycol- substituted 3,3′-difluorobenzidine derivative - has been synthesized, and its complexation with the host, cyclobis(paraquat-p-phenylene), has been investigated. This host-guest complex was then employed in the template-directed synthesis of a blue-colored [2]rotaxane. The color of this [2]rotaxane arises from the charge-transfer absorption band between the HOMO of the guest and the LUMO of the host. This host-guest complex, and the derived [2]rotaxane, completes the donor-acceptor-based RGB (red/green/blue) color complex set. © 2007 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/332726
ISSN
2023 Impact Factor: 4.9
2023 SCImago Journal Rankings: 1.245
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorIkeda, Taichi-
dc.contributor.authorAprahamian, Ivan-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:13:48Z-
dc.date.available2023-10-06T05:13:48Z-
dc.date.issued2007-
dc.identifier.citationOrganic Letters, 2007, v. 9, n. 8, p. 1481-1484-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10722/332726-
dc.description.abstractEquation presented A guest molecule - a bis-N-tetraethyleneglycol- substituted 3,3′-difluorobenzidine derivative - has been synthesized, and its complexation with the host, cyclobis(paraquat-p-phenylene), has been investigated. This host-guest complex was then employed in the template-directed synthesis of a blue-colored [2]rotaxane. The color of this [2]rotaxane arises from the charge-transfer absorption band between the HOMO of the guest and the LUMO of the host. This host-guest complex, and the derived [2]rotaxane, completes the donor-acceptor-based RGB (red/green/blue) color complex set. © 2007 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofOrganic Letters-
dc.titleBlue-colored donor-acceptor [2]rotaxane-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ol070170h-
dc.identifier.scopuseid_2-s2.0-34247494708-
dc.identifier.volume9-
dc.identifier.issue8-
dc.identifier.spage1481-
dc.identifier.epage1484-
dc.identifier.isiWOS:000245439000015-

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