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- Publisher Website: 10.1021/ol070052u
- Scopus: eid_2-s2.0-34147151108
- WOS: WOS:000245084300029
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Article: A clicked bistable [2]rotaxane
Title | A clicked bistable [2]rotaxane |
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Authors | |
Issue Date | 2007 |
Citation | Organic Letters, 2007, v. 9, n. 7, p. 1287-1290 How to Cite? |
Abstract | A universal diazide-terminated polyether, incorporating tetrathiafulvalene (TTF, green) and 1,5-dioxynaphthalene (DNP, red) units, was prepared and subsequently employed in the template-directed synthesis of a switchable donor/acceptor [2]rotaxane. The triazole rings (magenta), which are introduced into the rotaxane during requisite click reactions, do not present themselves as competing recognition sites for the tetracationic cyclophane (blue) as it is induced to switch between the TTF unit, when it becomes dicationic (green adorned with yellow extremities), and the DNP unit. © 2007 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/332724 |
ISSN | 2023 Impact Factor: 4.9 2023 SCImago Journal Rankings: 1.245 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Aprahamian, Ivan | - |
dc.contributor.author | Dichtel, William R. | - |
dc.contributor.author | Ikeda, Taichi | - |
dc.contributor.author | Heath, James R. | - |
dc.contributor.author | Stoddart, J. Fraser | - |
dc.date.accessioned | 2023-10-06T05:13:47Z | - |
dc.date.available | 2023-10-06T05:13:47Z | - |
dc.date.issued | 2007 | - |
dc.identifier.citation | Organic Letters, 2007, v. 9, n. 7, p. 1287-1290 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | http://hdl.handle.net/10722/332724 | - |
dc.description.abstract | A universal diazide-terminated polyether, incorporating tetrathiafulvalene (TTF, green) and 1,5-dioxynaphthalene (DNP, red) units, was prepared and subsequently employed in the template-directed synthesis of a switchable donor/acceptor [2]rotaxane. The triazole rings (magenta), which are introduced into the rotaxane during requisite click reactions, do not present themselves as competing recognition sites for the tetracationic cyclophane (blue) as it is induced to switch between the TTF unit, when it becomes dicationic (green adorned with yellow extremities), and the DNP unit. © 2007 American Chemical Society. | - |
dc.language | eng | - |
dc.relation.ispartof | Organic Letters | - |
dc.title | A clicked bistable [2]rotaxane | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1021/ol070052u | - |
dc.identifier.scopus | eid_2-s2.0-34147151108 | - |
dc.identifier.volume | 9 | - |
dc.identifier.issue | 7 | - |
dc.identifier.spage | 1287 | - |
dc.identifier.epage | 1290 | - |
dc.identifier.isi | WOS:000245084300029 | - |