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Article: Template-directed one-step synthesis of cyclic trimers by ADMET

TitleTemplate-directed one-step synthesis of cyclic trimers by ADMET
Authors
Issue Date2006
Citation
Journal of the American Chemical Society, 2006, v. 128, n. 48, p. 15358-15359 How to Cite?
AbstractA trifurcated template, containing three secondary dialkylammonium ion recognition sites for encirclement by a dibenzo [24]crown-8-containing acyclic diene, is used to promote acyclic diene metatheses (ADMET) catalyzed by ruthenium-alkylidene complexes, affording a cyclic trimer in 55% yield. Following this one-step, threefold ADMET reaction, the resulting cyclic trimer was isolated by preparative HPLC and characterized by NMR spectroscopy and mass spectrometry. Copyright © 2006 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/332713
ISSN
2023 Impact Factor: 14.4
2023 SCImago Journal Rankings: 5.489
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorHou, Hongyi-
dc.contributor.authorLeung, Ken C.F.-
dc.contributor.authorLanari, Daniela-
dc.contributor.authorNelson, Alshakim-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorGrubbs, Robert H.-
dc.date.accessioned2023-10-06T05:13:41Z-
dc.date.available2023-10-06T05:13:41Z-
dc.date.issued2006-
dc.identifier.citationJournal of the American Chemical Society, 2006, v. 128, n. 48, p. 15358-15359-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/332713-
dc.description.abstractA trifurcated template, containing three secondary dialkylammonium ion recognition sites for encirclement by a dibenzo [24]crown-8-containing acyclic diene, is used to promote acyclic diene metatheses (ADMET) catalyzed by ruthenium-alkylidene complexes, affording a cyclic trimer in 55% yield. Following this one-step, threefold ADMET reaction, the resulting cyclic trimer was isolated by preparative HPLC and characterized by NMR spectroscopy and mass spectrometry. Copyright © 2006 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titleTemplate-directed one-step synthesis of cyclic trimers by ADMET-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ja065572j-
dc.identifier.pmid17131986-
dc.identifier.scopuseid_2-s2.0-33845327559-
dc.identifier.volume128-
dc.identifier.issue48-
dc.identifier.spage15358-
dc.identifier.epage15359-
dc.identifier.isiWOS:000242367000003-

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