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Article: Controlling Translational Isomerism in [2]Catenanes

TitleControlling Translational Isomerism in [2]Catenanes
Authors
Ashton, Peter R.Pérez‐García, LluïsaStoddart, J. FraserWhite, Andrew J.P.Williams, David J.
Keywordscatenanes
crown ethers
self‐assembly
translational isomerism
Issue Date1995
Citation
Angewandte Chemie International Edition in English, 1995, v. 34, n. 5, p. 571-574 How to Cite?
DOI: http://dx.doi.org/10.1002/anie.199505711
AbstractThe template‐directed synthesis of the [2]catenane 1‐4 PF6, in which a macrocyclic polyether is encircled by a tetracationic cyclophane, has been achieved in 58% yield. Of the four possible translational isomers, that shown on the right dominates in solution at low temperatures, according to 1H NMR spectroscopy. This isomer is the only one observed in the solid state. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
Persistent Identifierhttp://hdl.handle.net/10722/332703
ISSN
0570-0833
ISI Accession Number ID
WOS:A1995QP64600013

 

DC FieldValueLanguage
dc.contributor.authorAshton, Peter R.-
dc.contributor.authorPérez‐García, Lluïsa-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorWhite, Andrew J.P.-
dc.contributor.authorWilliams, David J.-
dc.date.accessioned2023-10-06T05:13:37Z-
dc.date.available2023-10-06T05:13:37Z-
dc.date.issued1995-
dc.identifier.citationAngewandte Chemie International Edition in English, 1995, v. 34, n. 5, p. 571-574-
dc.identifier.issn0570-0833-
dc.identifier.urihttp://hdl.handle.net/10722/332703-
dc.description.abstractThe template‐directed synthesis of the [2]catenane 1‐4 PF6, in which a macrocyclic polyether is encircled by a tetracationic cyclophane, has been achieved in 58% yield. Of the four possible translational isomers, that shown on the right dominates in solution at low temperatures, according to 1H NMR spectroscopy. This isomer is the only one observed in the solid state. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie International Edition in English-
dc.subjectcatenanes-
dc.subjectcrown ethers-
dc.subjectself‐assembly-
dc.subjecttranslational isomerism-
dc.titleControlling Translational Isomerism in [2]Catenanes-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.199505711-
dc.identifier.scopuseid_2-s2.0-33748245620-
dc.identifier.volume34-
dc.identifier.issue5-
dc.identifier.spage571-
dc.identifier.epage574-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:A1995QP64600013-

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