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- Scopus: eid_2-s2.0-33748239927
- WOS: WOS:A1995TF90400010
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Article: Kinetic Selection in the Template‐Directed Self‐Assembly of [2]Catenanes
| Title | Kinetic Selection in the Template‐Directed Self‐Assembly of [2]Catenanes |
|---|---|
| Authors | |
| Keywords | catenanes Curtin‐Hammett principle molecular recognition self‐assembly template effect |
| Issue Date | 1995 |
| Citation | Angewandte Chemie International Edition in English, 1995, v. 34, n. 21, p. 2378-2380 How to Cite? |
| Abstract | A kinetic template effect directs selection in competitive self‐assembly of tetracationic cyclophanes (represented by a circle) containing meta‐ or para‐linked 4,4′‐bipyridinium and/or bis(4‐pyridinium)ethylene units in the presence of competing crown ether templates (represented by a square or a triangle). The cyclophane fragments first couple covalently to form an intermediate (represented by an arc), and then the molecular recognition event strings the crown ether before the rate‐determining second covalent bond formation closes the ring. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany |
| Persistent Identifier | http://hdl.handle.net/10722/332699 |
| ISSN | |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Amabilino, David B. | - |
| dc.contributor.author | Ashton, Peter R. | - |
| dc.contributor.author | Pérez‐García, Lluïsa | - |
| dc.contributor.author | Stoddart, J. Fraser | - |
| dc.date.accessioned | 2023-10-06T05:13:35Z | - |
| dc.date.available | 2023-10-06T05:13:35Z | - |
| dc.date.issued | 1995 | - |
| dc.identifier.citation | Angewandte Chemie International Edition in English, 1995, v. 34, n. 21, p. 2378-2380 | - |
| dc.identifier.issn | 0570-0833 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/332699 | - |
| dc.description.abstract | A kinetic template effect directs selection in competitive self‐assembly of tetracationic cyclophanes (represented by a circle) containing meta‐ or para‐linked 4,4′‐bipyridinium and/or bis(4‐pyridinium)ethylene units in the presence of competing crown ether templates (represented by a square or a triangle). The cyclophane fragments first couple covalently to form an intermediate (represented by an arc), and then the molecular recognition event strings the crown ether before the rate‐determining second covalent bond formation closes the ring. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany | - |
| dc.language | eng | - |
| dc.relation.ispartof | Angewandte Chemie International Edition in English | - |
| dc.subject | catenanes | - |
| dc.subject | Curtin‐Hammett principle | - |
| dc.subject | molecular recognition | - |
| dc.subject | self‐assembly | - |
| dc.subject | template effect | - |
| dc.title | Kinetic Selection in the Template‐Directed Self‐Assembly of [2]Catenanes | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/anie.199523781 | - |
| dc.identifier.scopus | eid_2-s2.0-33748239927 | - |
| dc.identifier.volume | 34 | - |
| dc.identifier.issue | 21 | - |
| dc.identifier.spage | 2378 | - |
| dc.identifier.epage | 2380 | - |
| dc.identifier.eissn | 1521-3773 | - |
| dc.identifier.isi | WOS:A1995TF90400010 | - |