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- Publisher Website: 10.1002/anie.199204781
- Scopus: eid_2-s2.0-33748233294
- WOS: WOS:A1992JD99400031
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Article: Designing Synthetic Cationic Molecular Receptors for Alcohols
| Title | Designing Synthetic Cationic Molecular Receptors for Alcohols |
|---|---|
| Authors | |
| Issue Date | 1992 |
| Citation | Angewandte Chemie International Edition in English, 1992, v. 31, n. 4, p. 478-480 How to Cite? |
| Abstract | The monoprotonation of diaza‐12‐crown‐6 derivatives converts these macrocycles to hosts for short‐chain alcohols; the association constant Ka is as high as 47 M−1. For the neutral diaza crown ether, on the other hand, Ka is only 1.1 M−1. X‐ray structure investigations show that the alcohol (R = Me) is held in place by two hydrogen bonds (see right). R = Me, Et, nPr, nBu; R′ = PhCH2, PhCH2CH2 (Figure Presented.) Copyright © 1992 by VCH Verlagsgesellschaft mbH, Germany |
| Persistent Identifier | http://hdl.handle.net/10722/332696 |
| ISSN | |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Méndez, Luis | - |
| dc.contributor.author | Singleton, Raymond | - |
| dc.contributor.author | Slawin, Alexandra M.Z. | - |
| dc.contributor.author | Stoddart, J. Fraser | - |
| dc.contributor.author | Williams, David J. | - |
| dc.contributor.author | Williams, M. Kevin | - |
| dc.date.accessioned | 2023-10-06T05:13:34Z | - |
| dc.date.available | 2023-10-06T05:13:34Z | - |
| dc.date.issued | 1992 | - |
| dc.identifier.citation | Angewandte Chemie International Edition in English, 1992, v. 31, n. 4, p. 478-480 | - |
| dc.identifier.issn | 0570-0833 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/332696 | - |
| dc.description.abstract | The monoprotonation of diaza‐12‐crown‐6 derivatives converts these macrocycles to hosts for short‐chain alcohols; the association constant Ka is as high as 47 M−1. For the neutral diaza crown ether, on the other hand, Ka is only 1.1 M−1. X‐ray structure investigations show that the alcohol (R = Me) is held in place by two hydrogen bonds (see right). R = Me, Et, nPr, nBu; R′ = PhCH2, PhCH2CH2 (Figure Presented.) Copyright © 1992 by VCH Verlagsgesellschaft mbH, Germany | - |
| dc.language | eng | - |
| dc.relation.ispartof | Angewandte Chemie International Edition in English | - |
| dc.title | Designing Synthetic Cationic Molecular Receptors for Alcohols | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/anie.199204781 | - |
| dc.identifier.scopus | eid_2-s2.0-33748233294 | - |
| dc.identifier.volume | 31 | - |
| dc.identifier.issue | 4 | - |
| dc.identifier.spage | 478 | - |
| dc.identifier.epage | 480 | - |
| dc.identifier.eissn | 1521-3773 | - |
| dc.identifier.isi | WOS:A1992JD99400031 | - |