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- Publisher Website: 10.1007/128_009
- Scopus: eid_2-s2.0-33747586881
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Article: Towards a rational design of molecular switches and sensors from their basic building blocks
Title | Towards a rational design of molecular switches and sensors from their basic building blocks |
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Authors | |
Keywords | Kinetics Molecular shuttles Rotaxanes Thermodynamics Translational isomerism |
Issue Date | 2005 |
Citation | Topics in Current Chemistry, 2005, v. 262, p. 99-132 How to Cite? |
Abstract | A fundamental understanding of the thermodynamics and kinetics of mechanically interlocked molecules, such as [2]rotaxanes, will contribute to a more rational design of new molecular machines. This Chapter describes the influence of chemical modifications and the role of the physical environment on the ground state thermodynamics and the shuttling and switching kinetics of several tetrathiafulvalene- and 1,5-dioxynaphthalene-containing [2]rotaxanes. A comparison between the properties of these bistable rotaxanes and model host-guest complexes of the corresponding π-electron donating recognition units with the π-electron accepting cyclophane, cyclobis(paraquat-p- phenylene), has been made, resulting in useful guidelines for the design of new bistable rotaxanes with specific, desirable physical performances. |
Persistent Identifier | http://hdl.handle.net/10722/332683 |
ISSN | 2015 Impact Factor: 4.014 2020 SCImago Journal Rankings: 1.944 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Moonen, Nicolle N.P. | - |
dc.contributor.author | Flood, Amar H. | - |
dc.contributor.author | Fernández, Juan M. | - |
dc.contributor.author | Stoddart, J. Fraser | - |
dc.date.accessioned | 2023-10-06T05:13:28Z | - |
dc.date.available | 2023-10-06T05:13:28Z | - |
dc.date.issued | 2005 | - |
dc.identifier.citation | Topics in Current Chemistry, 2005, v. 262, p. 99-132 | - |
dc.identifier.issn | 0340-1022 | - |
dc.identifier.uri | http://hdl.handle.net/10722/332683 | - |
dc.description.abstract | A fundamental understanding of the thermodynamics and kinetics of mechanically interlocked molecules, such as [2]rotaxanes, will contribute to a more rational design of new molecular machines. This Chapter describes the influence of chemical modifications and the role of the physical environment on the ground state thermodynamics and the shuttling and switching kinetics of several tetrathiafulvalene- and 1,5-dioxynaphthalene-containing [2]rotaxanes. A comparison between the properties of these bistable rotaxanes and model host-guest complexes of the corresponding π-electron donating recognition units with the π-electron accepting cyclophane, cyclobis(paraquat-p- phenylene), has been made, resulting in useful guidelines for the design of new bistable rotaxanes with specific, desirable physical performances. | - |
dc.language | eng | - |
dc.relation.ispartof | Topics in Current Chemistry | - |
dc.subject | Kinetics | - |
dc.subject | Molecular shuttles | - |
dc.subject | Rotaxanes | - |
dc.subject | Thermodynamics | - |
dc.subject | Translational isomerism | - |
dc.title | Towards a rational design of molecular switches and sensors from their basic building blocks | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1007/128_009 | - |
dc.identifier.scopus | eid_2-s2.0-33747586881 | - |
dc.identifier.volume | 262 | - |
dc.identifier.spage | 99 | - |
dc.identifier.epage | 132 | - |
dc.identifier.isi | WOS:000236039000004 | - |