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Article: Templated synthesis of interlocked molecules

TitleTemplated synthesis of interlocked molecules
Authors
KeywordsCatenanes
Dynamic chemistry
Molecular machines
Multivalency
Rotaxanes
Issue Date2005
Citation
Topics in Current Chemistry, 2005, v. 249, p. 203-259 How to Cite?
AbstractMechanically interlocked molecular compounds can be synthesized in high yields by using template-directed assistance to covalent synthesis. Catenanes and rotaxanes are two classes of mechanically interlocked molecules that have been prepared using a variety of methods such as "clipping", "slipping", and "threading-followed-by-stoppering", under both kinetic and thermodynamic regimes. These different methods have utilized a range of templates such as transistion metals, π-donor/π-acceptors, and hydrogen-bonding motifs. Multivalency has emerged as another tool to aid and abet the supramolecularly assisted synthesis of mechanically interlocked molecules. Recent advances in our understanding of the nature of the mechanical bond has led to the construction of molecular machines with controllable motions that have, in one instance, been introduced into molecular electronic devices. © Springer-Verlag Berlin Heidelberg 2005.
Persistent Identifierhttp://hdl.handle.net/10722/332637
ISSN
2015 Impact Factor: 4.014
2020 SCImago Journal Rankings: 1.944
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorAricó, Fabio-
dc.contributor.authorBadjic, Jovica D.-
dc.contributor.authorCantrill, Stuart J.-
dc.contributor.authorFlood, Amar H.-
dc.contributor.authorLeung, Ken C.F.-
dc.contributor.authorLiu, Yi-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:13:06Z-
dc.date.available2023-10-06T05:13:06Z-
dc.date.issued2005-
dc.identifier.citationTopics in Current Chemistry, 2005, v. 249, p. 203-259-
dc.identifier.issn0340-1022-
dc.identifier.urihttp://hdl.handle.net/10722/332637-
dc.description.abstractMechanically interlocked molecular compounds can be synthesized in high yields by using template-directed assistance to covalent synthesis. Catenanes and rotaxanes are two classes of mechanically interlocked molecules that have been prepared using a variety of methods such as "clipping", "slipping", and "threading-followed-by-stoppering", under both kinetic and thermodynamic regimes. These different methods have utilized a range of templates such as transistion metals, π-donor/π-acceptors, and hydrogen-bonding motifs. Multivalency has emerged as another tool to aid and abet the supramolecularly assisted synthesis of mechanically interlocked molecules. Recent advances in our understanding of the nature of the mechanical bond has led to the construction of molecular machines with controllable motions that have, in one instance, been introduced into molecular electronic devices. © Springer-Verlag Berlin Heidelberg 2005.-
dc.languageeng-
dc.relation.ispartofTopics in Current Chemistry-
dc.subjectCatenanes-
dc.subjectDynamic chemistry-
dc.subjectMolecular machines-
dc.subjectMultivalency-
dc.subjectRotaxanes-
dc.titleTemplated synthesis of interlocked molecules-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1007/b104330-
dc.identifier.scopuseid_2-s2.0-27744561333-
dc.identifier.volume249-
dc.identifier.spage203-
dc.identifier.epage259-
dc.identifier.isiWOS:000234111900004-

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