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- Publisher Website: 10.1021/ol051599g
- Scopus: eid_2-s2.0-25444472910
- PMID: 16146390
- WOS: WOS:000231858100038
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Article: Template-directed olefin cross metathesis
Title | Template-directed olefin cross metathesis |
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Authors | |
Issue Date | 2005 |
Citation | Organic Letters, 2005, v. 7, n. 19, p. 4213-4216 How to Cite? |
Abstract | (Figure Presented) A template containing two secondary dialkylammonium ion recognition sites for encirclement by olefin-bearing dibenzo[24]crown-8 derivatives has been used to promote olefin cross metatheses with ruthenium-alkylidene catalysts. For monoolefin monomers, the rates of metatheses and yields of the dimers are both amplified in the presence of the template. Likewise, for a diolefin monomer, the yield of the dimer is enhanced in the presence of the template under conditions where higher oligomers are not formed. © 2005 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/332625 |
ISSN | 2023 Impact Factor: 4.9 2023 SCImago Journal Rankings: 1.245 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Cantrill, Stuart J. | - |
dc.contributor.author | Grubbs, Robert H. | - |
dc.contributor.author | Lanari, Daniela | - |
dc.contributor.author | Leung, Ken C.F. | - |
dc.contributor.author | Nelson, Alshakim | - |
dc.contributor.author | Poulin-Kerstien, Katherine G. | - |
dc.contributor.author | Smidt, Sebastian P. | - |
dc.contributor.author | Stoddart, J. Fraser | - |
dc.contributor.author | Tirrell, David A. | - |
dc.date.accessioned | 2023-10-06T05:13:00Z | - |
dc.date.available | 2023-10-06T05:13:00Z | - |
dc.date.issued | 2005 | - |
dc.identifier.citation | Organic Letters, 2005, v. 7, n. 19, p. 4213-4216 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | http://hdl.handle.net/10722/332625 | - |
dc.description.abstract | (Figure Presented) A template containing two secondary dialkylammonium ion recognition sites for encirclement by olefin-bearing dibenzo[24]crown-8 derivatives has been used to promote olefin cross metatheses with ruthenium-alkylidene catalysts. For monoolefin monomers, the rates of metatheses and yields of the dimers are both amplified in the presence of the template. Likewise, for a diolefin monomer, the yield of the dimer is enhanced in the presence of the template under conditions where higher oligomers are not formed. © 2005 American Chemical Society. | - |
dc.language | eng | - |
dc.relation.ispartof | Organic Letters | - |
dc.title | Template-directed olefin cross metathesis | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1021/ol051599g | - |
dc.identifier.pmid | 16146390 | - |
dc.identifier.scopus | eid_2-s2.0-25444472910 | - |
dc.identifier.volume | 7 | - |
dc.identifier.issue | 19 | - |
dc.identifier.spage | 4213 | - |
dc.identifier.epage | 4216 | - |
dc.identifier.isi | WOS:000231858100038 | - |