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- Publisher Website: 10.1002/anie.200351558
- Scopus: eid_2-s2.0-0141522573
- PMID: 14502741
- WOS: WOS:000185544900015
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Article: Amplification of dynamic chiral crown ether complexes during cyclic acetal formation
Title | Amplification of dynamic chiral crown ether complexes during cyclic acetal formation |
---|---|
Authors | |
Keywords | Combinatorial chemistry Macrocycles Supramolecular chemistry Template synthesis Transacetalation |
Issue Date | 2003 |
Citation | Angewandte Chemie - International Edition, 2003, v. 42, n. 35, p. 4220-4224 How to Cite? |
Abstract | The dynamic duo: A more than tenfold increase in the yield of the chiral macropolycyclic polyether containing two 2,6-disubstituted 1,3,5,7-cis-tetraoxadecalin systems was obtained under thermodynamic conditions from a dynamic combinatorial virtual library with templating cesium ions (> 95 % yield, see schematic representation) relative to kinetic syntheses (< 8 % yields in their macropolycyclization steps), even when the same template was used. |
Persistent Identifier | http://hdl.handle.net/10722/332543 |
ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Fuchs, Benzion | - |
dc.contributor.author | Nelson, Alshakim | - |
dc.contributor.author | Star, Alexander | - |
dc.contributor.author | Stoddart, J. Fraser | - |
dc.contributor.author | Vidal, Sébastien | - |
dc.date.accessioned | 2023-10-06T05:12:20Z | - |
dc.date.available | 2023-10-06T05:12:20Z | - |
dc.date.issued | 2003 | - |
dc.identifier.citation | Angewandte Chemie - International Edition, 2003, v. 42, n. 35, p. 4220-4224 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10722/332543 | - |
dc.description.abstract | The dynamic duo: A more than tenfold increase in the yield of the chiral macropolycyclic polyether containing two 2,6-disubstituted 1,3,5,7-cis-tetraoxadecalin systems was obtained under thermodynamic conditions from a dynamic combinatorial virtual library with templating cesium ions (> 95 % yield, see schematic representation) relative to kinetic syntheses (< 8 % yields in their macropolycyclization steps), even when the same template was used. | - |
dc.language | eng | - |
dc.relation.ispartof | Angewandte Chemie - International Edition | - |
dc.subject | Combinatorial chemistry | - |
dc.subject | Macrocycles | - |
dc.subject | Supramolecular chemistry | - |
dc.subject | Template synthesis | - |
dc.subject | Transacetalation | - |
dc.title | Amplification of dynamic chiral crown ether complexes during cyclic acetal formation | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1002/anie.200351558 | - |
dc.identifier.pmid | 14502741 | - |
dc.identifier.scopus | eid_2-s2.0-0141522573 | - |
dc.identifier.volume | 42 | - |
dc.identifier.issue | 35 | - |
dc.identifier.spage | 4220 | - |
dc.identifier.epage | 4224 | - |
dc.identifier.isi | WOS:000185544900015 | - |