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Article: Amplification of dynamic chiral crown ether complexes during cyclic acetal formation

TitleAmplification of dynamic chiral crown ether complexes during cyclic acetal formation
Authors
Fuchs, BenzionNelson, AlshakimStar, AlexanderStoddart, J. FraserVidal, Sébastien
KeywordsCombinatorial chemistry
Macrocycles
Supramolecular chemistry
Template synthesis
Transacetalation
Issue Date2003
Citation
Angewandte Chemie - International Edition, 2003, v. 42, n. 35, p. 4220-4224 How to Cite?
DOI: http://dx.doi.org/10.1002/anie.200351558
AbstractThe dynamic duo: A more than tenfold increase in the yield of the chiral macropolycyclic polyether containing two 2,6-disubstituted 1,3,5,7-cis-tetraoxadecalin systems was obtained under thermodynamic conditions from a dynamic combinatorial virtual library with templating cesium ions (> 95 % yield, see schematic representation) relative to kinetic syntheses (< 8 % yields in their macropolycyclization steps), even when the same template was used.
Persistent Identifierhttp://hdl.handle.net/10722/332543
ISSN
1433-7851
2023 Impact Factor: 16.1
2023 SCImago Journal Rankings: 5.300
ISI Accession Number ID
WOS:000185544900015

 

DC FieldValueLanguage
dc.contributor.authorFuchs, Benzion-
dc.contributor.authorNelson, Alshakim-
dc.contributor.authorStar, Alexander-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorVidal, Sébastien-
dc.date.accessioned2023-10-06T05:12:20Z-
dc.date.available2023-10-06T05:12:20Z-
dc.date.issued2003-
dc.identifier.citationAngewandte Chemie - International Edition, 2003, v. 42, n. 35, p. 4220-4224-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/332543-
dc.description.abstractThe dynamic duo: A more than tenfold increase in the yield of the chiral macropolycyclic polyether containing two 2,6-disubstituted 1,3,5,7-cis-tetraoxadecalin systems was obtained under thermodynamic conditions from a dynamic combinatorial virtual library with templating cesium ions (> 95 % yield, see schematic representation) relative to kinetic syntheses (< 8 % yields in their macropolycyclization steps), even when the same template was used.-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie - International Edition-
dc.subjectCombinatorial chemistry-
dc.subjectMacrocycles-
dc.subjectSupramolecular chemistry-
dc.subjectTemplate synthesis-
dc.subjectTransacetalation-
dc.titleAmplification of dynamic chiral crown ether complexes during cyclic acetal formation-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.200351558-
dc.identifier.pmid14502741-
dc.identifier.scopuseid_2-s2.0-0141522573-
dc.identifier.volume42-
dc.identifier.issue35-
dc.identifier.spage4220-
dc.identifier.epage4224-
dc.identifier.isiWOS:000185544900015-

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