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- Publisher Website: 10.1002/1521-3773(20010518)40:10<1870::AID-ANIE1870>3.0.CO;2-Z
- Scopus: eid_2-s2.0-0035906693
- WOS: WOS:000168891800010
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Article: Template-directed synthesis of a [2]rotaxane by the clipping under thermodynamic control of a crown ether like macrocycle around a dialkylammonium ion
| Title | Template-directed synthesis of a [2]rotaxane by the clipping under thermodynamic control of a crown ether like macrocycle around a dialkylammonium ion |
|---|---|
| Authors | |
| Keywords | Macrocycles Rotaxanes Self-assembly Template synthesis |
| Issue Date | 2001 |
| Citation | Angewandte Chemie - International Edition, 2001, v. 40, n. 10, p. 1870-1875 How to Cite? |
| Abstract | A dumbbell-shaped dialkylammonium ion (see scheme) templates the formation, about its NH2+ center, of a crown ether like macrocycle under thermodynamic control from dialdehyde and diamine precursors. The imine-containing [2]rotaxane that ensues was converted by reduction into a kinetically stable interlocked molecule, which has been characterized in the solid state by X-ray crystallography in both free vase and salt forms. |
| Persistent Identifier | http://hdl.handle.net/10722/332498 |
| ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Glink, Peter T. | - |
| dc.contributor.author | Oliva, Ana I. | - |
| dc.contributor.author | Fraser Stoddart, J. | - |
| dc.contributor.author | White, Andrew J.P. | - |
| dc.contributor.author | Williams, David J. | - |
| dc.date.accessioned | 2023-10-06T05:11:59Z | - |
| dc.date.available | 2023-10-06T05:11:59Z | - |
| dc.date.issued | 2001 | - |
| dc.identifier.citation | Angewandte Chemie - International Edition, 2001, v. 40, n. 10, p. 1870-1875 | - |
| dc.identifier.issn | 1433-7851 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/332498 | - |
| dc.description.abstract | A dumbbell-shaped dialkylammonium ion (see scheme) templates the formation, about its NH2+ center, of a crown ether like macrocycle under thermodynamic control from dialdehyde and diamine precursors. The imine-containing [2]rotaxane that ensues was converted by reduction into a kinetically stable interlocked molecule, which has been characterized in the solid state by X-ray crystallography in both free vase and salt forms. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Angewandte Chemie - International Edition | - |
| dc.subject | Macrocycles | - |
| dc.subject | Rotaxanes | - |
| dc.subject | Self-assembly | - |
| dc.subject | Template synthesis | - |
| dc.title | Template-directed synthesis of a [2]rotaxane by the clipping under thermodynamic control of a crown ether like macrocycle around a dialkylammonium ion | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/1521-3773(20010518)40:10<1870::AID-ANIE1870>3.0.CO;2-Z | - |
| dc.identifier.scopus | eid_2-s2.0-0035906693 | - |
| dc.identifier.volume | 40 | - |
| dc.identifier.issue | 10 | - |
| dc.identifier.spage | 1870 | - |
| dc.identifier.epage | 1875 | - |
| dc.identifier.isi | WOS:000168891800010 | - |