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Article: A rotaxane-like complex with controlled-release characteristics

TitleA rotaxane-like complex with controlled-release characteristics
Authors
Chiu, Sheng HsienRowan, Stuart J.Cantrill, Stuart J.Glink, Peter T.Garrell, Robin L.Stoddart, J. Fraser
Issue Date2000
Citation
Organic Letters, 2000, v. 2, n. 23, p. 3631-3634 How to Cite?
DOI: http://dx.doi.org/10.1021/ol006525d
Abstract(matrix presented) A rotaxane-like complex, based on a dumbbell-shaped component containing an NH2+ recognition site for a [25]crown-8 ring component and a slippage stopper in the form of a p-(tert-butyl)phenyl group, has been synthesized by a "threading-followed-by-stoppering" approach. The half-life for dissociation of this complex, which is very sensitive to its environment, can be varied from minutes to months by changing the temperature and the polarity of the solvent.
Persistent Identifierhttp://hdl.handle.net/10722/332479
ISSN
1523-7060
2023 Impact Factor: 4.9
2023 SCImago Journal Rankings: 1.245
ISI Accession Number ID
WOS:000165301700026

 

DC FieldValueLanguage
dc.contributor.authorChiu, Sheng Hsien-
dc.contributor.authorRowan, Stuart J.-
dc.contributor.authorCantrill, Stuart J.-
dc.contributor.authorGlink, Peter T.-
dc.contributor.authorGarrell, Robin L.-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:11:50Z-
dc.date.available2023-10-06T05:11:50Z-
dc.date.issued2000-
dc.identifier.citationOrganic Letters, 2000, v. 2, n. 23, p. 3631-3634-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10722/332479-
dc.description.abstract(matrix presented) A rotaxane-like complex, based on a dumbbell-shaped component containing an NH2+ recognition site for a [25]crown-8 ring component and a slippage stopper in the form of a p-(tert-butyl)phenyl group, has been synthesized by a "threading-followed-by-stoppering" approach. The half-life for dissociation of this complex, which is very sensitive to its environment, can be varied from minutes to months by changing the temperature and the polarity of the solvent.-
dc.languageeng-
dc.relation.ispartofOrganic Letters-
dc.titleA rotaxane-like complex with controlled-release characteristics-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ol006525d-
dc.identifier.pmid11073662-
dc.identifier.scopuseid_2-s2.0-0034676572-
dc.identifier.volume2-
dc.identifier.issue23-
dc.identifier.spage3631-
dc.identifier.epage3634-
dc.identifier.isiWOS:000165301700026-

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