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Article: Bent aromatic rings in naphthalene derivatives

TitleBent aromatic rings in naphthalene derivatives
Authors
Ashton, Peter R.Brown, George R.Foubister, Alan J.Smith, Diane R.Spencer, NeilStoddart, J. FraserWilliams, David J.
Issue Date1993
Citation
Tetrahedron Letters, 1993, v. 34, n. 51, p. 8333-8336 How to Cite?
DOI: http://dx.doi.org/10.1016/S0040-4039(00)61424-7
AbstractX-Ray crystallography and dynamic 1H NMR spectroscopy have revealed that 1,4,5,8-tetramethyl-, 1-bromomethyl-4,5,8-trimethyl-, and 1,8-bis(bromomethyl)-4,5-dimethyl-2,3,6,7-tetrabromonaphthalene - 3, 4, and 5, respectively - have severely distorted naphthalene nuclei in the solid state that also correspond to the gross conformations that occupy appreciable (ΔG‡∼16 kcal mol-1) energy wells in the solution state. © 1993.
Persistent Identifierhttp://hdl.handle.net/10722/332364
ISSN
0040-4039
2023 Impact Factor: 1.5
2023 SCImago Journal Rankings: 0.323
ISI Accession Number ID
WOS:A1993MN26300039

 

DC FieldValueLanguage
dc.contributor.authorAshton, Peter R.-
dc.contributor.authorBrown, George R.-
dc.contributor.authorFoubister, Alan J.-
dc.contributor.authorSmith, Diane R.-
dc.contributor.authorSpencer, Neil-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorWilliams, David J.-
dc.date.accessioned2023-10-06T05:10:53Z-
dc.date.available2023-10-06T05:10:53Z-
dc.date.issued1993-
dc.identifier.citationTetrahedron Letters, 1993, v. 34, n. 51, p. 8333-8336-
dc.identifier.issn0040-4039-
dc.identifier.urihttp://hdl.handle.net/10722/332364-
dc.description.abstractX-Ray crystallography and dynamic 1H NMR spectroscopy have revealed that 1,4,5,8-tetramethyl-, 1-bromomethyl-4,5,8-trimethyl-, and 1,8-bis(bromomethyl)-4,5-dimethyl-2,3,6,7-tetrabromonaphthalene - 3, 4, and 5, respectively - have severely distorted naphthalene nuclei in the solid state that also correspond to the gross conformations that occupy appreciable (ΔG‡∼16 kcal mol-1) energy wells in the solution state. © 1993.-
dc.languageeng-
dc.relation.ispartofTetrahedron Letters-
dc.titleBent aromatic rings in naphthalene derivatives-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0040-4039(00)61424-7-
dc.identifier.scopuseid_2-s2.0-0027759737-
dc.identifier.volume34-
dc.identifier.issue51-
dc.identifier.spage8333-
dc.identifier.epage8336-
dc.identifier.isiWOS:A1993MN26300039-

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