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- Publisher Website: 10.1021/ol0171362
- Scopus: eid_2-s2.0-0001681390
- PMID: 11843590
- WOS: WOS:000173885800022
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Article: Poised on the brink between a bistable complex and a compound
| Title | Poised on the brink between a bistable complex and a compound |
|---|---|
| Authors | |
| Issue Date | 2002 |
| Citation | Organic Letters, 2002, v. 4, n. 4, p. 557-560 How to Cite? |
| Abstract | (figure presented) An enmeshed supramolecular complex, based on a semi-dumbbell-shaped component containing an asymmetrically substituted tetrathiafulvalene site and a 1,5-dioxynaphthalene site for encirclement by a cyclobis(paraquat-p-phenylene) ring component and with a "speed bump" in the form of an thiomethyl group situated between the two recognition sites, has been self-assembled. This complex is a mixture in acetone solution of two slowly interconverting [2]pseudorotaxanes, one of which is on the verge of being a [2]rotaxane at room temperature. |
| Persistent Identifier | http://hdl.handle.net/10722/332308 |
| ISSN | 2023 Impact Factor: 4.9 2023 SCImago Journal Rankings: 1.245 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Jeppesen, Jan Oskar | - |
| dc.contributor.author | Becher, Jan | - |
| dc.contributor.author | Stoddart, J. Fraser | - |
| dc.date.accessioned | 2023-10-06T05:10:27Z | - |
| dc.date.available | 2023-10-06T05:10:27Z | - |
| dc.date.issued | 2002 | - |
| dc.identifier.citation | Organic Letters, 2002, v. 4, n. 4, p. 557-560 | - |
| dc.identifier.issn | 1523-7060 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/332308 | - |
| dc.description.abstract | (figure presented) An enmeshed supramolecular complex, based on a semi-dumbbell-shaped component containing an asymmetrically substituted tetrathiafulvalene site and a 1,5-dioxynaphthalene site for encirclement by a cyclobis(paraquat-p-phenylene) ring component and with a "speed bump" in the form of an thiomethyl group situated between the two recognition sites, has been self-assembled. This complex is a mixture in acetone solution of two slowly interconverting [2]pseudorotaxanes, one of which is on the verge of being a [2]rotaxane at room temperature. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Organic Letters | - |
| dc.title | Poised on the brink between a bistable complex and a compound | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1021/ol0171362 | - |
| dc.identifier.pmid | 11843590 | - |
| dc.identifier.scopus | eid_2-s2.0-0001681390 | - |
| dc.identifier.volume | 4 | - |
| dc.identifier.issue | 4 | - |
| dc.identifier.spage | 557 | - |
| dc.identifier.epage | 560 | - |
| dc.identifier.isi | WOS:000173885800022 | - |