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Article: Conception and birth of new receptor chemistry from dibenzo-18-crown-6
Title | Conception and birth of new receptor chemistry from dibenzo-18-crown-6 |
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Authors | |
Issue Date | 1988 |
Citation | Pure and Applied Chemistry, 1988, v. 60, n. 4, p. 467-472 How to Cite? |
Abstract | The ability of dibenzo-3n-crown-n ethers (n = 6–12) to form stable adducts in solution with a range of neutral and cationic transition metal complexes is discussed. The concept of second sphere coordination can be enlarged to one of molecular recognition involving the whole gamut of non-covalent bonding interactions. It is described how this research led logically to molecular receptors for the bipyridinium herbicides Diquat and Paraquat. In particular, dibenzo-30-crown-10 forms a highly selective 1:1 complex with Diquat whereas, a constitutional isomer, bispara-phenylene-34-crown-10, is a good molecular receptor for Paraquat. © 1988 IUPAC |
Persistent Identifier | http://hdl.handle.net/10722/332299 |
ISSN | 2023 Impact Factor: 2.0 2023 SCImago Journal Rankings: 0.435 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Stoddart, J. Fraser | - |
dc.date.accessioned | 2023-10-06T05:10:23Z | - |
dc.date.available | 2023-10-06T05:10:23Z | - |
dc.date.issued | 1988 | - |
dc.identifier.citation | Pure and Applied Chemistry, 1988, v. 60, n. 4, p. 467-472 | - |
dc.identifier.issn | 0033-4545 | - |
dc.identifier.uri | http://hdl.handle.net/10722/332299 | - |
dc.description.abstract | The ability of dibenzo-3n-crown-n ethers (n = 6–12) to form stable adducts in solution with a range of neutral and cationic transition metal complexes is discussed. The concept of second sphere coordination can be enlarged to one of molecular recognition involving the whole gamut of non-covalent bonding interactions. It is described how this research led logically to molecular receptors for the bipyridinium herbicides Diquat and Paraquat. In particular, dibenzo-30-crown-10 forms a highly selective 1:1 complex with Diquat whereas, a constitutional isomer, bispara-phenylene-34-crown-10, is a good molecular receptor for Paraquat. © 1988 IUPAC | - |
dc.language | eng | - |
dc.relation.ispartof | Pure and Applied Chemistry | - |
dc.title | Conception and birth of new receptor chemistry from dibenzo-18-crown-6 | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1351/pac198860040467 | - |
dc.identifier.scopus | eid_2-s2.0-0001436869 | - |
dc.identifier.volume | 60 | - |
dc.identifier.issue | 4 | - |
dc.identifier.spage | 467 | - |
dc.identifier.epage | 472 | - |
dc.identifier.eissn | 1365-3075 | - |
dc.identifier.isi | WOS:A1988N465600005 | - |