File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Toward interlocked molecules beyond catenanes and rotaxanes

TitleToward interlocked molecules beyond catenanes and rotaxanes
Authors
Issue Date2000
Citation
Organic Letters, 2000, v. 2, n. 19, p. 2943-2946 How to Cite?
AbstractA linear bis secondary dialkylammonium ion-containing scaffold - based upon an anthracenyl core-has been synthesized. It has been demonstrated that it is possible to dock either one or two dibenzo[24]crown-8 (DB24C8) macrocycles onto this scaffold to afford either a [2]-or [3]pseudorotaxane, respectively. In solution, the association constants for the formation of each of these species has been quantified by employing 1H NMR spectroscopy, and both species survive in the "gas phase" as evidenced by FAB mass spectrometry. Additionally, the X-ray crystal superstructure of the [3]pseudorotaxane has been determined.
Persistent Identifierhttp://hdl.handle.net/10722/332258
ISSN
2023 Impact Factor: 4.9
2023 SCImago Journal Rankings: 1.245
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorChang, Theresa-
dc.contributor.authorHeiss, Aaron M.-
dc.contributor.authorCantrill, Stuart J.-
dc.contributor.authorFyfe, Matthew C.T.-
dc.contributor.authorPease, Anthony R.-
dc.contributor.authorRowan, Stuart J.-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorWilliams, David J.-
dc.date.accessioned2023-10-06T05:10:05Z-
dc.date.available2023-10-06T05:10:05Z-
dc.date.issued2000-
dc.identifier.citationOrganic Letters, 2000, v. 2, n. 19, p. 2943-2946-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10722/332258-
dc.description.abstractA linear bis secondary dialkylammonium ion-containing scaffold - based upon an anthracenyl core-has been synthesized. It has been demonstrated that it is possible to dock either one or two dibenzo[24]crown-8 (DB24C8) macrocycles onto this scaffold to afford either a [2]-or [3]pseudorotaxane, respectively. In solution, the association constants for the formation of each of these species has been quantified by employing 1H NMR spectroscopy, and both species survive in the "gas phase" as evidenced by FAB mass spectrometry. Additionally, the X-ray crystal superstructure of the [3]pseudorotaxane has been determined.-
dc.languageeng-
dc.relation.ispartofOrganic Letters-
dc.titleToward interlocked molecules beyond catenanes and rotaxanes-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ol006187g-
dc.identifier.pmid10986078-
dc.identifier.scopuseid_2-s2.0-0000047771-
dc.identifier.volume2-
dc.identifier.issue19-
dc.identifier.spage2943-
dc.identifier.epage2946-
dc.identifier.isiWOS:000089386100007-

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats