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Article: Lamellar assembly and nanostructures of amphiphilic boron(iii) diketonates through suitable non-covalent interactions

TitleLamellar assembly and nanostructures of amphiphilic boron(iii) diketonates through suitable non-covalent interactions
Authors
Cao, JingjiePoon, Chun-TingChan, Michael Ho-YeungHong, Eugene Yau-HinCheng, Yat-HinHau, Franky Ka-WahWu, LixinYam, Vivian Wing-Wah
Issue Date28-Feb-2023
PublisherRoyal Society of Chemistry
Citation
Organic Chemistry Frontiers, 2023, v. 10, n. 7, p. 1694-1704 How to Cite?
DOI: http://dx.doi.org/10.1039/D3QO00031A
Abstract

A new class of amphiphilic boron(iii) diketonate compounds has been designed and synthesized. Thin 2D nanosheet assemblies were formed with lamellar packing, which are most likely driven by non-covalent pi-pi interactions and hydrophobic interactions in a THF-water solution mixture. Detailed studies of the self-assembly mechanism have been conducted with solvent- and temperature-dependent electronic absorption and emission experiments. The supramolecular nanostructures and morphologies have been established by TEM, AFM and XRD studies, leading to an understanding of the assembly of boron(iii) diketonate coordination materials.


Persistent Identifierhttp://hdl.handle.net/10722/331577
ISI Accession Number ID
WOS:000940530700001

 

DC FieldValueLanguage
dc.contributor.authorCao, Jingjie-
dc.contributor.authorPoon, Chun-Ting-
dc.contributor.authorChan, Michael Ho-Yeung-
dc.contributor.authorHong, Eugene Yau-Hin-
dc.contributor.authorCheng, Yat-Hin-
dc.contributor.authorHau, Franky Ka-Wah-
dc.contributor.authorWu, Lixin-
dc.contributor.authorYam, Vivian Wing-Wah-
dc.date.accessioned2023-09-21T06:57:04Z-
dc.date.available2023-09-21T06:57:04Z-
dc.date.issued2023-02-28-
dc.identifier.citationOrganic Chemistry Frontiers, 2023, v. 10, n. 7, p. 1694-1704-
dc.identifier.urihttp://hdl.handle.net/10722/331577-
dc.description.abstract<p>A new class of amphiphilic boron(iii) diketonate compounds has been designed and synthesized. Thin 2D nanosheet assemblies were formed with lamellar packing, which are most likely driven by non-covalent pi-pi interactions and hydrophobic interactions in a THF-water solution mixture. Detailed studies of the self-assembly mechanism have been conducted with solvent- and temperature-dependent electronic absorption and emission experiments. The supramolecular nanostructures and morphologies have been established by TEM, AFM and XRD studies, leading to an understanding of the assembly of boron(iii) diketonate coordination materials.<br></p>-
dc.languageeng-
dc.publisherRoyal Society of Chemistry-
dc.relation.ispartofOrganic Chemistry Frontiers-
dc.titleLamellar assembly and nanostructures of amphiphilic boron(iii) diketonates through suitable non-covalent interactions-
dc.typeArticle-
dc.identifier.doi10.1039/D3QO00031A-
dc.identifier.scopuseid_2-s2.0-85149226791-
dc.identifier.volume10-
dc.identifier.issue7-
dc.identifier.spage1694-
dc.identifier.epage1704-
dc.identifier.eissn2052-4129-
dc.identifier.isiWOS:000940530700001-
dc.identifier.issnl2052-4110-

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