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- Publisher Website: 10.1021/jacs.2c08551
- Scopus: eid_2-s2.0-85143855091
- WOS: WOS:000895518400001
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Article: Toward the Design and Construction of Supramolecular Functional Molecular Materials Based on Metal–Metal Interactions
Title | Toward the Design and Construction of Supramolecular Functional Molecular Materials Based on Metal–Metal Interactions |
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Authors | |
Issue Date | 9-Dec-2022 |
Publisher | American Chemical Society |
Citation | Journal of the American Chemical Society, 2022, v. 144, n. 50, p. 22805-22825 How to Cite? |
Abstract | Supramolecular functional materials represent an emerging class of materials that have been governed by the supramolecular chemistry of self-assembled molecules. Such high-order molecular hierarchies have been stabilized by various kinds of noncovalent intermolecular forces including hydrogen bonding, electrostatic, donor-acceptor, N-N stacking interactions, and dispersion forces. Recently, metal-metal interactions have also emerged as an unconventional type of noncovalent interaction that is unique in the metal complex system for the construction of self-assembled metal-based materials. These metal-metal interactions have further imparted the self-assembled materials with rich spectroscopic functionalities. However, the systematic control of these hierarchical architectures through metal-metal interactions remains challenging. In this Perspective, we aim to stimulate research direction in the field with the utilization of such intriguing and unique directional noncovalent metal-metal interactions as one of the driving forces, highlighting the roles and significance of metal-metal interactions and ultimately facilitating a controlled and rational design and synthesis of metallosupramolecular functional materials with rich spectroscopic properties and huge potential for various applications. |
Persistent Identifier | http://hdl.handle.net/10722/331571 |
ISSN | 2023 Impact Factor: 14.4 2023 SCImago Journal Rankings: 5.489 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Chan, Michael Ho-Yeung | - |
dc.contributor.author | Yam, Vivian Wing-Wah | - |
dc.date.accessioned | 2023-09-21T06:57:01Z | - |
dc.date.available | 2023-09-21T06:57:01Z | - |
dc.date.issued | 2022-12-09 | - |
dc.identifier.citation | Journal of the American Chemical Society, 2022, v. 144, n. 50, p. 22805-22825 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10722/331571 | - |
dc.description.abstract | <p>Supramolecular functional materials represent an emerging class of materials that have been governed by the supramolecular chemistry of self-assembled molecules. Such high-order molecular hierarchies have been stabilized by various kinds of noncovalent intermolecular forces including hydrogen bonding, electrostatic, donor-acceptor, N-N stacking interactions, and dispersion forces. Recently, metal-metal interactions have also emerged as an unconventional type of noncovalent interaction that is unique in the metal complex system for the construction of self-assembled metal-based materials. These metal-metal interactions have further imparted the self-assembled materials with rich spectroscopic functionalities. However, the systematic control of these hierarchical architectures through metal-metal interactions remains challenging. In this Perspective, we aim to stimulate research direction in the field with the utilization of such intriguing and unique directional noncovalent metal-metal interactions as one of the driving forces, highlighting the roles and significance of metal-metal interactions and ultimately facilitating a controlled and rational design and synthesis of metallosupramolecular functional materials with rich spectroscopic properties and huge potential for various applications.<br></p> | - |
dc.language | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation.ispartof | Journal of the American Chemical Society | - |
dc.title | Toward the Design and Construction of Supramolecular Functional Molecular Materials Based on Metal–Metal Interactions | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/jacs.2c08551 | - |
dc.identifier.scopus | eid_2-s2.0-85143855091 | - |
dc.identifier.volume | 144 | - |
dc.identifier.issue | 50 | - |
dc.identifier.spage | 22805 | - |
dc.identifier.epage | 22825 | - |
dc.identifier.eissn | 1520-5126 | - |
dc.identifier.isi | WOS:000895518400001 | - |
dc.identifier.issnl | 0002-7863 | - |