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- Publisher Website: 10.1021/jacs.3c02571
- Scopus: eid_2-s2.0-85160709256
- WOS: WOS:001012128500001
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Article: Step-by-Step Electrocrystallization Processes to Make Multiblock Magnetic Molecular Heterostructures
Title | Step-by-Step Electrocrystallization Processes to Make Multiblock Magnetic Molecular Heterostructures |
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Authors | |
Issue Date | 17-May-2023 |
Publisher | American Chemical Society |
Citation | Journal of the American Chemical Society, 2023, v. 145, n. 26, p. 14288-14297 How to Cite? |
Abstract | Assembling conductive or magnetic heterostructures by bulk inorganic materials is important for making functional electronic or spintronic devices, such as semiconductive p-doped and n-doped silicon for P–N junction diodes, alternating ferromagnetic and nonmagnetic conductive layers used in giant magnetoresistance (GMR). Nonetheless, there have been few demonstrations of conductive or magnetic heterostructures made by discrete molecules. It is of fundamental interest to prepare and investigate heterostructures based on molecular conductors or molecular magnets, such as single-molecule magnets (SMMs). Herein, we demonstrate the fabrication of a series of molecular heterostructures composed of (TTF)2M(pdms)2 (TTF = tetrathiafulvalene, M = Co(II), Zn(II), Ni(II), H2pdms = 1,2-bis(methanesulfonamido)benzene) multiple building blocks through a well-controlled step-by-step electrocrystallization growth process, where the Co(pdms)2, Ni(pdms)2, and Zn(pdms)2 anionic complex is a SMM, paramagnetic, and diamagnetic molecule, respectively. Magnetic and SMM properties of the heterostructures were characterized and compared to the parentage (TTF)2Co(pdms)2 complex. This study presents the first methodology for creating molecule-based magnetic heterostructural systems by electrocrystallization. |
Persistent Identifier | http://hdl.handle.net/10722/331372 |
ISSN | 2023 Impact Factor: 14.4 2023 SCImago Journal Rankings: 5.489 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Wan, Qingyun | - |
dc.contributor.author | Wakizaka, Masanori | - |
dc.contributor.author | Funakoshi, Nobuto | - |
dc.contributor.author | Shen, Yongbing | - |
dc.contributor.author | Che, Chi-Ming | - |
dc.contributor.author | Yamashita, Masahiro | - |
dc.date.accessioned | 2023-09-21T06:55:10Z | - |
dc.date.available | 2023-09-21T06:55:10Z | - |
dc.date.issued | 2023-05-17 | - |
dc.identifier.citation | Journal of the American Chemical Society, 2023, v. 145, n. 26, p. 14288-14297 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10722/331372 | - |
dc.description.abstract | <p>Assembling conductive or magnetic heterostructures by bulk inorganic materials is important for making functional electronic or spintronic devices, such as semiconductive p-doped and n-doped silicon for P–N junction diodes, alternating ferromagnetic and nonmagnetic conductive layers used in giant magnetoresistance (GMR). Nonetheless, there have been few demonstrations of conductive or magnetic heterostructures made by discrete molecules. It is of fundamental interest to prepare and investigate heterostructures based on molecular conductors or molecular magnets, such as single-molecule magnets (SMMs). Herein, we demonstrate the fabrication of a series of molecular heterostructures composed of (TTF)<sub>2</sub>M(pdms)<sub>2</sub> (TTF = tetrathiafulvalene, M = Co(II), Zn(II), Ni(II), H<sub>2</sub>pdms = 1,2-bis(methanesulfonamido)benzene) multiple building blocks through a well-controlled step-by-step electrocrystallization growth process, where the Co(pdms)<sub>2</sub>, Ni(pdms)<sub>2</sub>, and Zn(pdms)<sub>2</sub> anionic complex is a SMM, paramagnetic, and diamagnetic molecule, respectively. Magnetic and SMM properties of the heterostructures were characterized and compared to the parentage (TTF)<sub>2</sub>Co(pdms)<sub>2</sub> complex. This study presents the first methodology for creating molecule-based magnetic heterostructural systems by electrocrystallization.</p> | - |
dc.language | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation.ispartof | Journal of the American Chemical Society | - |
dc.title | Step-by-Step Electrocrystallization Processes to Make Multiblock Magnetic Molecular Heterostructures | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/jacs.3c02571 | - |
dc.identifier.scopus | eid_2-s2.0-85160709256 | - |
dc.identifier.volume | 145 | - |
dc.identifier.issue | 26 | - |
dc.identifier.spage | 14288 | - |
dc.identifier.epage | 14297 | - |
dc.identifier.eissn | 1520-5126 | - |
dc.identifier.isi | WOS:001012128500001 | - |
dc.identifier.issnl | 0002-7863 | - |