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- Publisher Website: 10.3390/magnetochemistry9030077
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Article: A New Organic Conductor of Tetramethyltetraselenafulvalene (TMTSF) with a Magnetic Dy(III) Complex
| Title | A New Organic Conductor of Tetramethyltetraselenafulvalene (TMTSF) with a Magnetic Dy(III) Complex |
|---|---|
| Authors | |
| Keywords | Dysprosium(III) electro-crystallization organic conductor TMTSF |
| Issue Date | 6-Mar-2023 |
| Publisher | MDPI |
| Citation | Magnetochemistry, 2023, v. 9, n. 3 How to Cite? |
| Abstract | A new molecular conductor of (TMTSF)5[Dy(NCS)4(NO3)2]CHCl3 was prepared using the electrochemical oxidation method. The complex crystallizes in the Cmc21 (36) space group, where the partially-oxidized TMTSF molecules form a 1D (one-dimensional) column structure. The crystal shows a semiconducting behavior with a room temperature conductivity of 0.2 S·cm−1 and an activation energy of 34 meV at ambient pressure. |
| Persistent Identifier | http://hdl.handle.net/10722/331371 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Wan, Qingyun | - |
| dc.contributor.author | Wakizaka, Masanori | - |
| dc.contributor.author | Zhang, Haitao | - |
| dc.contributor.author | Shen, Yongbing | - |
| dc.contributor.author | Funakoshi, Nobuto | - |
| dc.contributor.author | Che, Chi-Ming | - |
| dc.contributor.author | Takaishi, Shinya | - |
| dc.contributor.author | Yamashita, Masahiro | - |
| dc.date.accessioned | 2023-09-21T06:55:09Z | - |
| dc.date.available | 2023-09-21T06:55:09Z | - |
| dc.date.issued | 2023-03-06 | - |
| dc.identifier.citation | Magnetochemistry, 2023, v. 9, n. 3 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/331371 | - |
| dc.description.abstract | <p>A new molecular conductor of (TMTSF)<sub>5</sub>[Dy(NCS)<sub>4</sub>(NO<sub>3</sub>)<sub>2</sub>]CHCl<sub>3</sub> was prepared using the electrochemical oxidation method. The complex crystallizes in the Cmc2<sub>1</sub> (36) space group, where the partially-oxidized TMTSF molecules form a 1D (one-dimensional) column structure. The crystal shows a semiconducting behavior with a room temperature conductivity of 0.2 S·cm<sup>−1</sup> and an activation energy of 34 meV at ambient pressure.<br></p> | - |
| dc.language | eng | - |
| dc.publisher | MDPI | - |
| dc.relation.ispartof | Magnetochemistry | - |
| dc.rights | This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License. | - |
| dc.subject | Dysprosium(III) | - |
| dc.subject | electro-crystallization | - |
| dc.subject | organic conductor | - |
| dc.subject | TMTSF | - |
| dc.title | A New Organic Conductor of Tetramethyltetraselenafulvalene (TMTSF) with a Magnetic Dy(III) Complex | - |
| dc.type | Article | - |
| dc.description.nature | published_or_final_version | - |
| dc.identifier.doi | 10.3390/magnetochemistry9030077 | - |
| dc.identifier.scopus | eid_2-s2.0-85152675665 | - |
| dc.identifier.volume | 9 | - |
| dc.identifier.issue | 3 | - |
| dc.identifier.eissn | 2312-7481 | - |
| dc.identifier.isi | WOS:000959964500001 | - |
| dc.identifier.issnl | 2312-7481 | - |