File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1039/d2qo01972h
- Scopus: eid_2-s2.0-85148458805
- WOS: WOS:000928682700001
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: Iron porphyrin-catalysed C(sp3)–H amination with alkyl azides for the synthesis of complex nitrogen-containing compounds
| Title | Iron porphyrin-catalysed C(sp3)–H amination with alkyl azides for the synthesis of complex nitrogen-containing compounds |
|---|---|
| Authors | |
| Issue Date | 7-Feb-2023 |
| Publisher | Royal Society of Chemistry |
| Citation | Organic Chemistry Frontiers, 2023, v. 10, n. 6, p. 1368-1374 How to Cite? |
| Abstract | Transition metal-catalysed direct C–N bond formation via nitrenoid (metal–imido/nitrene complexes) insertion, such as C–H bond amination, is a powerful strategy for preparing nitrogen-containing organic compounds. In this context, metal catalysts based on iron are appealing due to iron's high Earth abundance and biocompatibility. Herein, we demonstrate that iron(III) NHC porphyrin-catalysed C(sp3)–H amination with alkyl azides, using [FeIII(TDCPP)(IMe)2]I (H2TDCPP = tetrakis(2,6-dichlorophenyl)porphyrin, IMe = 1,3-dimethylimidazol-2-ylidene) as a catalyst, offers a complementary approach for the synthesis of structurally complex organic compounds as exemplified by the synthesis of a panel of nitrogen-containing skeletons that are representative examples of various families of natural products and bioactive compounds. |
| Persistent Identifier | http://hdl.handle.net/10722/331368 |
| ISSN | 2023 SCImago Journal Rankings: 1.016 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Fan, Jianqiang | - |
| dc.contributor.author | Wang, Ye | - |
| dc.contributor.author | Hu, Xuefu | - |
| dc.contributor.author | Liu, Yungen | - |
| dc.contributor.author | Che, Chi-Ming | - |
| dc.date.accessioned | 2023-09-21T06:55:07Z | - |
| dc.date.available | 2023-09-21T06:55:07Z | - |
| dc.date.issued | 2023-02-07 | - |
| dc.identifier.citation | Organic Chemistry Frontiers, 2023, v. 10, n. 6, p. 1368-1374 | - |
| dc.identifier.issn | 2052-4110 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/331368 | - |
| dc.description.abstract | <p>Transition metal-catalysed direct C–N bond formation <em>via</em> nitrenoid (metal–imido/nitrene complexes) insertion, such as C–H bond amination, is a powerful strategy for preparing nitrogen-containing organic compounds. In this context, metal catalysts based on iron are appealing due to iron's high Earth abundance and biocompatibility. Herein, we demonstrate that iron(<small>III</small>) NHC porphyrin-catalysed C(sp<small><sup>3</sup></small>)–H amination with alkyl azides, using [Fe<small><sup>III</sup></small>(TDCPP)(IMe)<small><sub>2</sub></small>]I (H<small><sub>2</sub></small>TDCPP = tetrakis(2,6-dichlorophenyl)porphyrin, IMe = 1,3-dimethylimidazol-2-ylidene) as a catalyst, offers a complementary approach for the synthesis of structurally complex organic compounds as exemplified by the synthesis of a panel of nitrogen-containing skeletons that are representative examples of various families of natural products and bioactive compounds.<br></p> | - |
| dc.language | eng | - |
| dc.publisher | Royal Society of Chemistry | - |
| dc.relation.ispartof | Organic Chemistry Frontiers | - |
| dc.title | Iron porphyrin-catalysed C(sp3)–H amination with alkyl azides for the synthesis of complex nitrogen-containing compounds | - |
| dc.type | Article | - |
| dc.identifier.doi | 10.1039/d2qo01972h | - |
| dc.identifier.scopus | eid_2-s2.0-85148458805 | - |
| dc.identifier.volume | 10 | - |
| dc.identifier.issue | 6 | - |
| dc.identifier.spage | 1368 | - |
| dc.identifier.epage | 1374 | - |
| dc.identifier.eissn | 2052-4129 | - |
| dc.identifier.isi | WOS:000928682700001 | - |
| dc.identifier.issnl | 2052-4110 | - |