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- Publisher Website: 10.1073/pnas.2209188120
- Scopus: eid_2-s2.0-85150129590
- PMID: 36913568
- WOS: WOS:000980501000004
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Article: Fluctuations in local shear-fault energy produce unique and dominating strengthening in metastable complex concentrated alloys
Title | Fluctuations in local shear-fault energy produce unique and dominating strengthening in metastable complex concentrated alloys |
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Authors | |
Keywords | dislocation resistance high-entropy alloys modeling of strengthening shear-fault fluctuations special atomic motifs |
Issue Date | 13-Mar-2023 |
Publisher | National Academy of Sciences |
Citation | Proceedings of the National Academy of Sciences, 2023, v. 120, n. 12 How to Cite? |
Abstract | Local chemical short-range ordering (SRO) and spatial fluctuations of planar fault energy are important features of multi-element and metastable complex concentrated alloys (CCAs). Arising from them, dislocations in such alloys are distinctively wavy in both static and migrating conditions; yet, such effects on strength have remained unknown. In this work, molecular dynamics simulations are used to show that the wavy configurations of dislocations and their jumpy motion in a prototypic CCA of NiCoCr are due to the local fluctuations of the energy of SRO shear-faulting that accompanies dislocation motion, with the dislocation getting pinned at sites of hard atomic motifs (HAMs) associated with high local shear-fault energies. Unlike the global averaged shear-fault energy which in general will subdue on successive dislocation passes, the local fluctuations in the fault energy always remain in a CCA, thus offering a strength contribution that is unique in such alloys. Analysis of the magnitude of this form of dislocation resistance shows that this is dominating over contributions due to elastic misfit of alloying elements and is in good agreement with strengths predicted from molecular dynamics simulations and experiments. This work has unfolded the physical basis of strength in CCAs, which is important for the development of these alloys into useful structural materials. |
Persistent Identifier | http://hdl.handle.net/10722/331092 |
ISSN | 2023 Impact Factor: 9.4 2023 SCImago Journal Rankings: 3.737 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Li, W | - |
dc.contributor.author | Lyu, S | - |
dc.contributor.author | Chen, Y | - |
dc.contributor.author | Ngan, AHW | - |
dc.date.accessioned | 2023-09-21T06:52:40Z | - |
dc.date.available | 2023-09-21T06:52:40Z | - |
dc.date.issued | 2023-03-13 | - |
dc.identifier.citation | Proceedings of the National Academy of Sciences, 2023, v. 120, n. 12 | - |
dc.identifier.issn | 0027-8424 | - |
dc.identifier.uri | http://hdl.handle.net/10722/331092 | - |
dc.description.abstract | <p>Local chemical short-range ordering (SRO) and spatial fluctuations of planar fault energy are important features of multi-element and metastable complex concentrated alloys (CCAs). Arising from them, dislocations in such alloys are distinctively wavy in both static and migrating conditions; yet, such effects on strength have remained unknown. In this work, molecular dynamics simulations are used to show that the wavy configurations of dislocations and their jumpy motion in a prototypic CCA of NiCoCr are due to the local fluctuations of the energy of SRO shear-faulting that accompanies dislocation motion, with the dislocation getting pinned at sites of hard atomic motifs (HAMs) associated with high local shear-fault energies. Unlike the global averaged shear-fault energy which in general will subdue on successive dislocation passes, the local fluctuations in the fault energy always remain in a CCA, thus offering a strength contribution that is unique in such alloys. Analysis of the magnitude of this form of dislocation resistance shows that this is dominating over contributions due to elastic misfit of alloying elements and is in good agreement with strengths predicted from molecular dynamics simulations and experiments. This work has unfolded the physical basis of strength in CCAs, which is important for the development of these alloys into useful structural materials.<br></p> | - |
dc.language | eng | - |
dc.publisher | National Academy of Sciences | - |
dc.relation.ispartof | Proceedings of the National Academy of Sciences | - |
dc.rights | This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License. | - |
dc.subject | dislocation resistance | - |
dc.subject | high-entropy alloys | - |
dc.subject | modeling of strengthening | - |
dc.subject | shear-fault fluctuations | - |
dc.subject | special atomic motifs | - |
dc.title | Fluctuations in local shear-fault energy produce unique and dominating strengthening in metastable complex concentrated alloys | - |
dc.type | Article | - |
dc.identifier.doi | 10.1073/pnas.2209188120 | - |
dc.identifier.pmid | 36913568 | - |
dc.identifier.scopus | eid_2-s2.0-85150129590 | - |
dc.identifier.volume | 120 | - |
dc.identifier.issue | 12 | - |
dc.identifier.eissn | 1091-6490 | - |
dc.identifier.isi | WOS:000980501000004 | - |
dc.publisher.place | WASHINGTON | - |
dc.identifier.issnl | 0027-8424 | - |