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- Publisher Website: 10.1002/anie.202104028
- Scopus: eid_2-s2.0-85107335523
- PMID: 33942452
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Article: General Synthesis of Ordered Mesoporous Carbonaceous Hybrid Nanostructures with Molecularly Dispersed Polyoxometallates
Title | General Synthesis of Ordered Mesoporous Carbonaceous Hybrid Nanostructures with Molecularly Dispersed Polyoxometallates |
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Authors | |
Keywords | biomass hydrothermal carbonization molecularly dispersed polyoxometalates ordered mesopore single-molecule heterogeneous catalyst |
Issue Date | 2021 |
Citation | Angewandte Chemie - International Edition, 2021, v. 60, n. 28, p. 15556-15562 How to Cite? |
Abstract | Hybrid nanomaterials with controlled dimensions, intriguing components and ordered structures have attracted significant attention in nanoscience and technology. Herein, we report a facile and green polyoxometallate (POM)-assisted hydrothermal carbonization strategy for synthesis of carbonaceous hybrid nanomaterials with molecularly dispersed POMs and ordered mesopores. By using various polyoxometallates such as ammonium phosphomolybdate, silicotungstic acid, and phosphotungstic acid, our approach can be generalized to synthesize ordered mesoporous hybrid nanostructures with diverse compositions and morphologies (nanosheet-assembled hierarchical architectures, nanospheres, and nanorods). Moreover, the ordered mesoporous nanosheet-assembled hierarchical hybrids with molecularly dispersed POMs exhibit remarkable catalytic activity toward the dehydration of tert-butanol with the high isobutene selectivity (100 %) and long-term catalytic durability (80 h). |
Persistent Identifier | http://hdl.handle.net/10722/329715 |
ISSN | 2021 Impact Factor: 16.823 2020 SCImago Journal Rankings: 5.831 |
DC Field | Value | Language |
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dc.contributor.author | Chen, Chunhong | - |
dc.contributor.author | Mao, Shanjun | - |
dc.contributor.author | Tan, Chaoliang | - |
dc.contributor.author | Wang, Zhe | - |
dc.contributor.author | Ge, Yiyao | - |
dc.contributor.author | Ma, Qinglang | - |
dc.contributor.author | Zhang, Xiao | - |
dc.contributor.author | Qi, Guodong | - |
dc.contributor.author | Xu, Jun | - |
dc.contributor.author | Fan, Zhanxi | - |
dc.contributor.author | Wang, Yong | - |
dc.date.accessioned | 2023-08-09T03:34:48Z | - |
dc.date.available | 2023-08-09T03:34:48Z | - |
dc.date.issued | 2021 | - |
dc.identifier.citation | Angewandte Chemie - International Edition, 2021, v. 60, n. 28, p. 15556-15562 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10722/329715 | - |
dc.description.abstract | Hybrid nanomaterials with controlled dimensions, intriguing components and ordered structures have attracted significant attention in nanoscience and technology. Herein, we report a facile and green polyoxometallate (POM)-assisted hydrothermal carbonization strategy for synthesis of carbonaceous hybrid nanomaterials with molecularly dispersed POMs and ordered mesopores. By using various polyoxometallates such as ammonium phosphomolybdate, silicotungstic acid, and phosphotungstic acid, our approach can be generalized to synthesize ordered mesoporous hybrid nanostructures with diverse compositions and morphologies (nanosheet-assembled hierarchical architectures, nanospheres, and nanorods). Moreover, the ordered mesoporous nanosheet-assembled hierarchical hybrids with molecularly dispersed POMs exhibit remarkable catalytic activity toward the dehydration of tert-butanol with the high isobutene selectivity (100 %) and long-term catalytic durability (80 h). | - |
dc.language | eng | - |
dc.relation.ispartof | Angewandte Chemie - International Edition | - |
dc.subject | biomass | - |
dc.subject | hydrothermal carbonization | - |
dc.subject | molecularly dispersed polyoxometalates | - |
dc.subject | ordered mesopore | - |
dc.subject | single-molecule heterogeneous catalyst | - |
dc.title | General Synthesis of Ordered Mesoporous Carbonaceous Hybrid Nanostructures with Molecularly Dispersed Polyoxometallates | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1002/anie.202104028 | - |
dc.identifier.pmid | 33942452 | - |
dc.identifier.scopus | eid_2-s2.0-85107335523 | - |
dc.identifier.volume | 60 | - |
dc.identifier.issue | 28 | - |
dc.identifier.spage | 15556 | - |
dc.identifier.epage | 15562 | - |
dc.identifier.eissn | 1521-3773 | - |