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- Publisher Website: 10.1021/acs.orglett.7b02906
- Scopus: eid_2-s2.0-85036521487
- PMID: 29129077
- WOS: WOS:000417229000005
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Article: Pd-Catalyzed Ortho C-H Hydroxylation of Benzaldehydes Using a Transient Directing Group
| Title | Pd-Catalyzed Ortho C-H Hydroxylation of Benzaldehydes Using a Transient Directing Group |
|---|---|
| Authors | |
| Issue Date | 2017 |
| Citation | Organic Letters, 2017, v. 19, n. 23, p. 6280-6283 How to Cite? |
| Abstract | The direct Pd-catalyzed ortho C-H hydroxylation of benzaldehydes was achieved using 4-chloroanthranilic acid as the transient directing group, 1-fluoro-2,4,6-trimethylpyridnium triflate as the bystanding oxidant, and p-toluenesulfonic acid as the putative oxygen nucleophile. The unusual C-H chlorination and polyfluoroalkoxylation reactions signaled the importance of external nucleophiles to the outcome of Pd(IV) reductive eliminations. |
| Persistent Identifier | http://hdl.handle.net/10722/327704 |
| ISSN | 2023 Impact Factor: 4.9 2023 SCImago Journal Rankings: 1.245 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Chen, Xiao Yang | - |
| dc.contributor.author | Ozturk, Seyma | - |
| dc.contributor.author | Sorensen, Erik J. | - |
| dc.date.accessioned | 2023-04-24T05:09:22Z | - |
| dc.date.available | 2023-04-24T05:09:22Z | - |
| dc.date.issued | 2017 | - |
| dc.identifier.citation | Organic Letters, 2017, v. 19, n. 23, p. 6280-6283 | - |
| dc.identifier.issn | 1523-7060 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/327704 | - |
| dc.description.abstract | The direct Pd-catalyzed ortho C-H hydroxylation of benzaldehydes was achieved using 4-chloroanthranilic acid as the transient directing group, 1-fluoro-2,4,6-trimethylpyridnium triflate as the bystanding oxidant, and p-toluenesulfonic acid as the putative oxygen nucleophile. The unusual C-H chlorination and polyfluoroalkoxylation reactions signaled the importance of external nucleophiles to the outcome of Pd(IV) reductive eliminations. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Organic Letters | - |
| dc.title | Pd-Catalyzed Ortho C-H Hydroxylation of Benzaldehydes Using a Transient Directing Group | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1021/acs.orglett.7b02906 | - |
| dc.identifier.pmid | 29129077 | - |
| dc.identifier.scopus | eid_2-s2.0-85036521487 | - |
| dc.identifier.volume | 19 | - |
| dc.identifier.issue | 23 | - |
| dc.identifier.spage | 6280 | - |
| dc.identifier.epage | 6283 | - |
| dc.identifier.eissn | 1523-7052 | - |
| dc.identifier.isi | WOS:000417229000005 | - |