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- Publisher Website: 10.1016/j.jhazmat.2022.129212
- Scopus: eid_2-s2.0-85130900623
- PMID: 35739734
- WOS: WOS:000807242000001
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Article: Oxygen-vacancy-enriched substrate-less SnOx /La-Sb anode for high-performance electrocatalytic oxidation of antibiotics in wastewater
Title | Oxygen-vacancy-enriched substrate-less SnO<inf>x</inf>/La-Sb anode for high-performance electrocatalytic oxidation of antibiotics in wastewater |
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Authors | |
Keywords | Electrochemical oxidation La doping Moxifloxacin Oxygen vacancy SnO electrode 2 |
Issue Date | 2022 |
Citation | Journal of Hazardous Materials, 2022, v. 436, article no. 129212 How to Cite? |
Abstract | Electrocatalytic oxidation is a promising technology for treating toxic organic pollutants in water and wastewater, but conventional Ti-based anodes often exhibit a short service life and low efficiency in application. Oxygen vacancy (OV)-based defect engineering is an effective activation method for enhancing the electrocatalytic activity of electrodes. Herein, the controllable formation of OV on the surface of a freestanding SnO2-Sb anode was achieved by the quantitative doping of La3+ into the SnO2 crystal structure of the anode for high-performance electrochemical wastewater treatment. The resultant SnOx/La-Sb anode degraded nearly 100% moxifloxacin (MOX, 10 mg L−1) in 30 min, with a low energy consumption of 0.09 kWh m−3. The SnOx/La-Sb anode with an OV density of 1.09% had the highest degradation rate constant (0.226 min−1), 8 times higher than that of the SnO2-Sb anode and 16 times higher than that of the state-of-the-art boron-doped diamond anode. La3+ doping-induced OV activated the anode surface for electrochemical reactions by boosting the interfacial electron transfer and •OH generation (103% increase). The novel 3D permeable SnOx/La-Sb anode also exhibited remarkable stability (predicted service life of 59 years) and high-rate performance (>98%) in a continuous flow-through treatment system (<1 min through the anode). |
Persistent Identifier | http://hdl.handle.net/10722/327408 |
ISSN | 2023 Impact Factor: 12.2 2023 SCImago Journal Rankings: 2.950 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Yang, Chao | - |
dc.contributor.author | Shang, Shanshan | - |
dc.contributor.author | Li, Xiao yan | - |
dc.date.accessioned | 2023-03-31T05:31:07Z | - |
dc.date.available | 2023-03-31T05:31:07Z | - |
dc.date.issued | 2022 | - |
dc.identifier.citation | Journal of Hazardous Materials, 2022, v. 436, article no. 129212 | - |
dc.identifier.issn | 0304-3894 | - |
dc.identifier.uri | http://hdl.handle.net/10722/327408 | - |
dc.description.abstract | Electrocatalytic oxidation is a promising technology for treating toxic organic pollutants in water and wastewater, but conventional Ti-based anodes often exhibit a short service life and low efficiency in application. Oxygen vacancy (OV)-based defect engineering is an effective activation method for enhancing the electrocatalytic activity of electrodes. Herein, the controllable formation of OV on the surface of a freestanding SnO2-Sb anode was achieved by the quantitative doping of La3+ into the SnO2 crystal structure of the anode for high-performance electrochemical wastewater treatment. The resultant SnOx/La-Sb anode degraded nearly 100% moxifloxacin (MOX, 10 mg L−1) in 30 min, with a low energy consumption of 0.09 kWh m−3. The SnOx/La-Sb anode with an OV density of 1.09% had the highest degradation rate constant (0.226 min−1), 8 times higher than that of the SnO2-Sb anode and 16 times higher than that of the state-of-the-art boron-doped diamond anode. La3+ doping-induced OV activated the anode surface for electrochemical reactions by boosting the interfacial electron transfer and •OH generation (103% increase). The novel 3D permeable SnOx/La-Sb anode also exhibited remarkable stability (predicted service life of 59 years) and high-rate performance (>98%) in a continuous flow-through treatment system (<1 min through the anode). | - |
dc.language | eng | - |
dc.relation.ispartof | Journal of Hazardous Materials | - |
dc.subject | Electrochemical oxidation | - |
dc.subject | La doping | - |
dc.subject | Moxifloxacin | - |
dc.subject | Oxygen vacancy | - |
dc.subject | SnO electrode 2 | - |
dc.title | Oxygen-vacancy-enriched substrate-less SnO<inf>x</inf>/La-Sb anode for high-performance electrocatalytic oxidation of antibiotics in wastewater | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/j.jhazmat.2022.129212 | - |
dc.identifier.pmid | 35739734 | - |
dc.identifier.scopus | eid_2-s2.0-85130900623 | - |
dc.identifier.volume | 436 | - |
dc.identifier.spage | article no. 129212 | - |
dc.identifier.epage | article no. 129212 | - |
dc.identifier.eissn | 1873-3336 | - |
dc.identifier.isi | WOS:000807242000001 | - |