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Article: Phenyl-Linked Anthracene-Based Macrocycles with Geometrically Tunable Optical Properties
Title | Phenyl-Linked Anthracene-Based Macrocycles with Geometrically Tunable Optical Properties |
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Authors | |
Keywords | anthracene macrocycles geometrically optical properties fluorescence |
Issue Date | 2020 |
Publisher | Thieme Open. The Journal's web site is located at https://www.thieme.de/en/thieme-chemistry/organic-materials-journal-information-136626.htm |
Citation | Organic Materials, 2020, v. 02 n. 04, p. 336-341 How to Cite? |
Abstract | Anthracene has been widely explored because of its intrinsic photophysical and photochemical properties. Here, two novel anthracene-based macrocycles (1 and 2) were designed and synthesized with para- and meta-phenylene spacers. X-ray crystallographic analysis demonstrates that compound 1 with para-phenylene spacers adopts a nearly planar structure, while compound 2 with meta-phenylene spacers displays a V-shaped geometry. The photophysical properties of the resultant macrocycles, which are structural isomers, are well studied using photoluminescence spectra and time-resolved absorption spectra, which are further corroborated by density functional theory calculations. The optical properties of these two novel macrocycles can be finely tuned via their geometries. |
Persistent Identifier | http://hdl.handle.net/10722/305274 |
ISSN |
DC Field | Value | Language |
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dc.contributor.author | Rong, MG | - |
dc.contributor.author | WANG, J | - |
dc.contributor.author | Low, KH | - |
dc.contributor.author | Liu, J | - |
dc.date.accessioned | 2021-10-20T10:07:06Z | - |
dc.date.available | 2021-10-20T10:07:06Z | - |
dc.date.issued | 2020 | - |
dc.identifier.citation | Organic Materials, 2020, v. 02 n. 04, p. 336-341 | - |
dc.identifier.issn | 2625-1825 | - |
dc.identifier.uri | http://hdl.handle.net/10722/305274 | - |
dc.description.abstract | Anthracene has been widely explored because of its intrinsic photophysical and photochemical properties. Here, two novel anthracene-based macrocycles (1 and 2) were designed and synthesized with para- and meta-phenylene spacers. X-ray crystallographic analysis demonstrates that compound 1 with para-phenylene spacers adopts a nearly planar structure, while compound 2 with meta-phenylene spacers displays a V-shaped geometry. The photophysical properties of the resultant macrocycles, which are structural isomers, are well studied using photoluminescence spectra and time-resolved absorption spectra, which are further corroborated by density functional theory calculations. The optical properties of these two novel macrocycles can be finely tuned via their geometries. | - |
dc.language | eng | - |
dc.publisher | Thieme Open. The Journal's web site is located at https://www.thieme.de/en/thieme-chemistry/organic-materials-journal-information-136626.htm | - |
dc.relation.ispartof | Organic Materials | - |
dc.rights | This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License. | - |
dc.subject | anthracene | - |
dc.subject | macrocycles | - |
dc.subject | geometrically | - |
dc.subject | optical properties | - |
dc.subject | fluorescence | - |
dc.title | Phenyl-Linked Anthracene-Based Macrocycles with Geometrically Tunable Optical Properties | - |
dc.type | Article | - |
dc.identifier.email | Rong, MG: rongmg@hku.hk | - |
dc.identifier.email | Low, KH: khlow@hku.hk | - |
dc.identifier.email | Liu, J: juliu@hku.hk | - |
dc.identifier.authority | Liu, J=rp02584 | - |
dc.description.nature | published_or_final_version | - |
dc.identifier.doi | 10.1055/s-0040-1721729 | - |
dc.identifier.hkuros | 327172 | - |
dc.identifier.volume | 02 | - |
dc.identifier.issue | 04 | - |
dc.identifier.spage | 336 | - |
dc.identifier.epage | 341 | - |
dc.publisher.place | Germany | - |