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Article: Metal-Quinoid Carbene Chemistry: From Bonding to C–H Activation Catalysis

TitleMetal-Quinoid Carbene Chemistry: From Bonding to C–H Activation Catalysis
Authors
Wang, HXWu, KChe, CM
Keywordsmetal carbenes
homogeneous catalysis
C–H functionalization
arylation
quinoid carbenes
Issue Date2021
PublisherThieme Publishing. The Journal's web site is located at http://www.thieme-chemistry.com/thieme-chemistry/journals/info/synlett/index.shtml
Citation
Synlett, 2021, v. 32 n. 3, p. 249-257 How to Cite?
DOI: http://dx.doi.org/10.1055/s-0040-1707221
AbstractThis account summarizes our recent work on metal-quinoid carbene (QC) chemistry including (a) dirhodium-catalyzed QC C(sp2)–H insertion reactions enabled by a C-centered carbene-transfer reactivity, (b) the isolation, characterization, and dual reactivity of Ru(II) porphyrin QC complexes, and (c) iridium(III) porphyrin-catalyzed QC C(sp3)–H insertion reaction initiated by an O-centered hydrogen-atom transfer reactivity of metal–QC species.
Persistent Identifierhttp://hdl.handle.net/10722/302453
ISSN
0936-5214
2023 Impact Factor: 1.7
2023 SCImago Journal Rankings: 0.450
ISI Accession Number ID
WOS:000612716500004

 

DC FieldValueLanguage
dc.contributor.authorWang, HX-
dc.contributor.authorWu, K-
dc.contributor.authorChe, CM-
dc.date.accessioned2021-09-06T03:32:31Z-
dc.date.available2021-09-06T03:32:31Z-
dc.date.issued2021-
dc.identifier.citationSynlett, 2021, v. 32 n. 3, p. 249-257-
dc.identifier.issn0936-5214-
dc.identifier.urihttp://hdl.handle.net/10722/302453-
dc.description.abstractThis account summarizes our recent work on metal-quinoid carbene (QC) chemistry including (a) dirhodium-catalyzed QC C(sp2)–H insertion reactions enabled by a C-centered carbene-transfer reactivity, (b) the isolation, characterization, and dual reactivity of Ru(II) porphyrin QC complexes, and (c) iridium(III) porphyrin-catalyzed QC C(sp3)–H insertion reaction initiated by an O-centered hydrogen-atom transfer reactivity of metal–QC species.-
dc.languageeng-
dc.publisherThieme Publishing. The Journal's web site is located at http://www.thieme-chemistry.com/thieme-chemistry/journals/info/synlett/index.shtml-
dc.relation.ispartofSynlett-
dc.rightsSynlett. Copyright © Thieme Publishing.-
dc.subjectmetal carbenes-
dc.subjecthomogeneous catalysis-
dc.subjectC–H functionalization-
dc.subjectarylation-
dc.subjectquinoid carbenes-
dc.titleMetal-Quinoid Carbene Chemistry: From Bonding to C–H Activation Catalysis-
dc.typeArticle-
dc.identifier.emailWu, K: wukai1@hku.hk-
dc.identifier.emailChe, CM: chemhead@hku.hk-
dc.identifier.authorityChe, CM=rp00670-
dc.description.naturepostprint-
dc.identifier.doi10.1055/s-0040-1707221-
dc.identifier.scopuseid_2-s2.0-85090430583-
dc.identifier.hkuros324869-
dc.identifier.volume32-
dc.identifier.issue3-
dc.identifier.spage249-
dc.identifier.epage257-
dc.identifier.isiWOS:000612716500004-
dc.publisher.placeGermany-

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