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- Publisher Website: 10.1055/s-0040-1707221
- Scopus: eid_2-s2.0-85090430583
- WOS: WOS:000612716500004
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Article: Metal-Quinoid Carbene Chemistry: From Bonding to C–H Activation Catalysis
Title | Metal-Quinoid Carbene Chemistry: From Bonding to C–H Activation Catalysis |
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Authors | |
Keywords | metal carbenes homogeneous catalysis C–H functionalization arylation quinoid carbenes |
Issue Date | 2021 |
Publisher | Thieme Publishing. The Journal's web site is located at http://www.thieme-chemistry.com/thieme-chemistry/journals/info/synlett/index.shtml |
Citation | Synlett, 2021, v. 32 n. 3, p. 249-257 How to Cite? |
Abstract | This account summarizes our recent work on metal-quinoid carbene (QC) chemistry including (a) dirhodium-catalyzed QC C(sp2)–H insertion reactions enabled by a C-centered carbene-transfer reactivity, (b) the isolation, characterization, and dual reactivity of Ru(II) porphyrin QC complexes, and (c) iridium(III) porphyrin-catalyzed QC C(sp3)–H insertion reaction initiated by an O-centered hydrogen-atom transfer reactivity of metal–QC species. |
Persistent Identifier | http://hdl.handle.net/10722/302453 |
ISSN | 2023 Impact Factor: 1.7 2023 SCImago Journal Rankings: 0.450 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Wang, HX | - |
dc.contributor.author | Wu, K | - |
dc.contributor.author | Che, CM | - |
dc.date.accessioned | 2021-09-06T03:32:31Z | - |
dc.date.available | 2021-09-06T03:32:31Z | - |
dc.date.issued | 2021 | - |
dc.identifier.citation | Synlett, 2021, v. 32 n. 3, p. 249-257 | - |
dc.identifier.issn | 0936-5214 | - |
dc.identifier.uri | http://hdl.handle.net/10722/302453 | - |
dc.description.abstract | This account summarizes our recent work on metal-quinoid carbene (QC) chemistry including (a) dirhodium-catalyzed QC C(sp2)–H insertion reactions enabled by a C-centered carbene-transfer reactivity, (b) the isolation, characterization, and dual reactivity of Ru(II) porphyrin QC complexes, and (c) iridium(III) porphyrin-catalyzed QC C(sp3)–H insertion reaction initiated by an O-centered hydrogen-atom transfer reactivity of metal–QC species. | - |
dc.language | eng | - |
dc.publisher | Thieme Publishing. The Journal's web site is located at http://www.thieme-chemistry.com/thieme-chemistry/journals/info/synlett/index.shtml | - |
dc.relation.ispartof | Synlett | - |
dc.rights | Synlett. Copyright © Thieme Publishing. | - |
dc.subject | metal carbenes | - |
dc.subject | homogeneous catalysis | - |
dc.subject | C–H functionalization | - |
dc.subject | arylation | - |
dc.subject | quinoid carbenes | - |
dc.title | Metal-Quinoid Carbene Chemistry: From Bonding to C–H Activation Catalysis | - |
dc.type | Article | - |
dc.identifier.email | Wu, K: wukai1@hku.hk | - |
dc.identifier.email | Che, CM: chemhead@hku.hk | - |
dc.identifier.authority | Che, CM=rp00670 | - |
dc.description.nature | postprint | - |
dc.identifier.doi | 10.1055/s-0040-1707221 | - |
dc.identifier.scopus | eid_2-s2.0-85090430583 | - |
dc.identifier.hkuros | 324869 | - |
dc.identifier.volume | 32 | - |
dc.identifier.issue | 3 | - |
dc.identifier.spage | 249 | - |
dc.identifier.epage | 257 | - |
dc.identifier.isi | WOS:000612716500004 | - |
dc.publisher.place | Germany | - |