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Article: Photoinduced Hydroarylation and Cyclization of Alkenes with Luminescent Platinum(II) Complexes

TitlePhotoinduced Hydroarylation and Cyclization of Alkenes with Luminescent Platinum(II) Complexes
Authors
Cheng, HLam, TLLiu, YTang, ZChe, CM
Keywordsaryl halides
hydroarylation
intramolecular cyclization
photocatalysis
platinum
Issue Date2021
PublisherWiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at https://onlinelibrary.wiley.com/journal/15213773
Citation
Angewandte Chemie (International Edition), 2021, v. 60 n. 3, p. 1383-1389 How to Cite?
DOI: http://dx.doi.org/10.1002/anie.202011841
AbstractPhotoinduced hydroarylation of alkenes is an appealing synthetic strategy for arene functionalization. Herein, we demonstrated that aryl radicals generated from electron-deficient aryl chlorides/bromides could be trapped by an array of terminal/internal aryl alkenes in the presence of [Pt(O^N^C^N)] under visible-light (410 nm) irradiation, affording anti-Markovnikov hydroarylated compounds in up to 95 % yield. Besides, a protocol for [Pt(O^N^C^N)]-catalyzed intramolecular photocyclization of acrylanilides to give structurally diverse 3,4-dihydroquinolinones has been developed.
Persistent Identifierhttp://hdl.handle.net/10722/302373
ISSN
1433-7851
2021 Impact Factor: 16.823
2020 SCImago Journal Rankings: 5.831
ISI Accession Number ID
WOS:000590083800001

 

DC FieldValueLanguage
dc.contributor.authorCheng, H-
dc.contributor.authorLam, TL-
dc.contributor.authorLiu, Y-
dc.contributor.authorTang, Z-
dc.contributor.authorChe, CM-
dc.date.accessioned2021-09-06T03:31:21Z-
dc.date.available2021-09-06T03:31:21Z-
dc.date.issued2021-
dc.identifier.citationAngewandte Chemie (International Edition), 2021, v. 60 n. 3, p. 1383-1389-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/302373-
dc.description.abstractPhotoinduced hydroarylation of alkenes is an appealing synthetic strategy for arene functionalization. Herein, we demonstrated that aryl radicals generated from electron-deficient aryl chlorides/bromides could be trapped by an array of terminal/internal aryl alkenes in the presence of [Pt(O^N^C^N)] under visible-light (410 nm) irradiation, affording anti-Markovnikov hydroarylated compounds in up to 95 % yield. Besides, a protocol for [Pt(O^N^C^N)]-catalyzed intramolecular photocyclization of acrylanilides to give structurally diverse 3,4-dihydroquinolinones has been developed.-
dc.languageeng-
dc.publisherWiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at https://onlinelibrary.wiley.com/journal/15213773-
dc.relation.ispartofAngewandte Chemie (International Edition)-
dc.rightsThis is the peer reviewed version of the following article: Angewandte Chemie (International Edition), which has been published in final form at https://doi.org/10.1002/anie.202011841. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.-
dc.subjectaryl halides-
dc.subjecthydroarylation-
dc.subjectintramolecular cyclization-
dc.subjectphotocatalysis-
dc.subjectplatinum-
dc.titlePhotoinduced Hydroarylation and Cyclization of Alkenes with Luminescent Platinum(II) Complexes-
dc.typeArticle-
dc.identifier.emailLam, TL: joeltl@hku.hk-
dc.identifier.emailChe, CM: chemhead@hku.hk-
dc.identifier.authorityLam, TL=rp02782-
dc.identifier.authorityChe, CM=rp00670-
dc.description.naturepostprint-
dc.identifier.doi10.1002/anie.202011841-
dc.identifier.pmid33029847-
dc.identifier.scopuseid_2-s2.0-85096640037-
dc.identifier.hkuros324866-
dc.identifier.volume60-
dc.identifier.issue3-
dc.identifier.spage1383-
dc.identifier.epage1389-
dc.identifier.isiWOS:000590083800001-
dc.publisher.placeGermany-

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