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- Publisher Website: 10.1002/chem.202003855
- Scopus: eid_2-s2.0-85096700287
- PMID: 33063382
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Article: High Efficiency Sky‐Blue Gold(III)‐TADF Emitters
Title | High Efficiency Sky‐Blue Gold(III)‐TADF Emitters |
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Authors | |
Issue Date | 2020 |
Publisher | Wiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistry |
Citation | Chemistry - A European Journal, 2020, v. 26 n. 67, p. 15718-15726 How to Cite? |
Abstract | Highly efficient sky-blue luminescent gold(III) complexes with emission quantum yields up to 82 %, lifetimes down to 0.67 μs and emission peak maxima at 470–484 nm were prepared through a consideration of pincer gold(III) donor–acceptor complexes. Photophysical studies and time-dependent density functional theory (TDDFT) calculations revealed that the emission nature of these gold(III) complexes is most consistent with TADF. Solution-processed OLEDs with these gold(III) complexes as dopants afforded electroluminescence maxima at 465–473 nm with FWHM of 64–67 nm and maximum external quantum efficiencies (EQEs) of up to 15.25 %. This research demonstrates the first example of gold(III)-OLEDs showing electroluminescence maxima at smaller than 470 nm, and highlights the potential of using gold(III)-TADF emitters in the development of high efficiency blue OLEDs and blue emissive dopant in WOLEDs. |
Persistent Identifier | http://hdl.handle.net/10722/302372 |
ISSN | 2023 Impact Factor: 3.9 2023 SCImago Journal Rankings: 1.058 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Zhou, D | - |
dc.contributor.author | Cheng, G | - |
dc.contributor.author | Tong, GSM | - |
dc.contributor.author | Che, CM | - |
dc.date.accessioned | 2021-09-06T03:31:21Z | - |
dc.date.available | 2021-09-06T03:31:21Z | - |
dc.date.issued | 2020 | - |
dc.identifier.citation | Chemistry - A European Journal, 2020, v. 26 n. 67, p. 15718-15726 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | http://hdl.handle.net/10722/302372 | - |
dc.description.abstract | Highly efficient sky-blue luminescent gold(III) complexes with emission quantum yields up to 82 %, lifetimes down to 0.67 μs and emission peak maxima at 470–484 nm were prepared through a consideration of pincer gold(III) donor–acceptor complexes. Photophysical studies and time-dependent density functional theory (TDDFT) calculations revealed that the emission nature of these gold(III) complexes is most consistent with TADF. Solution-processed OLEDs with these gold(III) complexes as dopants afforded electroluminescence maxima at 465–473 nm with FWHM of 64–67 nm and maximum external quantum efficiencies (EQEs) of up to 15.25 %. This research demonstrates the first example of gold(III)-OLEDs showing electroluminescence maxima at smaller than 470 nm, and highlights the potential of using gold(III)-TADF emitters in the development of high efficiency blue OLEDs and blue emissive dopant in WOLEDs. | - |
dc.language | eng | - |
dc.publisher | Wiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistry | - |
dc.relation.ispartof | Chemistry - A European Journal | - |
dc.rights | This is the peer reviewed version of the following article: Chemistry - A European Journal, 2020, v. 26 n. 67, p. 15718-15726, which has been published in final form at https://doi.org/10.1002/chem.202003855. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | - |
dc.title | High Efficiency Sky‐Blue Gold(III)‐TADF Emitters | - |
dc.type | Article | - |
dc.identifier.email | Zhou, D: dlzhou@connect.hku.hk | - |
dc.identifier.email | Tong, GSM: tongsm@hku.hk | - |
dc.identifier.email | Che, CM: chemhead@hku.hk | - |
dc.identifier.authority | Cheng, G=rp02145 | - |
dc.identifier.authority | Tong, GSM=rp00790 | - |
dc.identifier.authority | Che, CM=rp00670 | - |
dc.description.nature | postprint | - |
dc.identifier.doi | 10.1002/chem.202003855 | - |
dc.identifier.pmid | 33063382 | - |
dc.identifier.scopus | eid_2-s2.0-85096700287 | - |
dc.identifier.hkuros | 324865 | - |
dc.identifier.volume | 26 | - |
dc.identifier.issue | 67 | - |
dc.identifier.spage | 15718 | - |
dc.identifier.epage | 15726 | - |
dc.identifier.isi | WOS:000588037200001 | - |
dc.publisher.place | Germany | - |