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- Publisher Website: 10.1016/j.matdes.2016.02.109
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Article: Migration of sulphur in thermal barrier coatings during heat treatment
Title | Migration of sulphur in thermal barrier coatings during heat treatment |
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Authors | |
Keywords | Thermal barrier coatings (TBCs) Adhesion Oxidation Transmission electron microscopy (TEM) Second ion mass spectrometry (SIMS) Sulphur |
Issue Date | 2016 |
Citation | Materials and Design, 2016, v. 97, p. 364-371 How to Cite? |
Abstract | The sulphur effect in thermal barrier coatings (TBCs) mainly refers to a segregation of sulphur at the interface between thermally grown oxide (TGO) and the bond coat, which significantly deteriorates scale adhesion to alloys. Restricted by the extremely low concentrations of sulphur (0-10 ppm) in TBCs, previous investigations using conventional analytical techniques failed to provide a complete mechanism for the migration of sulphur. In this study, high resolution secondary ion mass spectrometry (NanoSIMS) was employed to detect trace sulphur distributions in commercial TBCs. After heat treatments, sulphur segregates at three typical areas in TBCs: (1) the yttria stabilized zirconia (YSZ) top coat; (2) the TGO/bond coat interface and (3) the grit blasted surface. This indicates that during heat treatment a significant outward diffusion of sulphur occurs from the superalloy to YSZ top coat through the TGO, and a possible mechanism for the migration of sulphur in TBCs is described. The undesired "sulphur effect" on scale adhesion was suggested to be caused by the formation of residual sulphides beneath the alumina scale with weaker ionic bonding to alloy cations. Possible solutions are suggested aiming to alleviate the sulphur effect in TBCs. |
Persistent Identifier | http://hdl.handle.net/10722/301796 |
ISSN | 2023 Impact Factor: 7.6 2023 SCImago Journal Rankings: 1.684 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Bai, Mingwen | - |
dc.contributor.author | Jiang, Haibo | - |
dc.contributor.author | Chen, Ying | - |
dc.contributor.author | Chen, Yiqiang | - |
dc.contributor.author | Grovenor, Chris | - |
dc.contributor.author | Zhao, Xiaofeng | - |
dc.contributor.author | Xiao, Ping | - |
dc.date.accessioned | 2021-08-19T02:20:45Z | - |
dc.date.available | 2021-08-19T02:20:45Z | - |
dc.date.issued | 2016 | - |
dc.identifier.citation | Materials and Design, 2016, v. 97, p. 364-371 | - |
dc.identifier.issn | 0264-1275 | - |
dc.identifier.uri | http://hdl.handle.net/10722/301796 | - |
dc.description.abstract | The sulphur effect in thermal barrier coatings (TBCs) mainly refers to a segregation of sulphur at the interface between thermally grown oxide (TGO) and the bond coat, which significantly deteriorates scale adhesion to alloys. Restricted by the extremely low concentrations of sulphur (0-10 ppm) in TBCs, previous investigations using conventional analytical techniques failed to provide a complete mechanism for the migration of sulphur. In this study, high resolution secondary ion mass spectrometry (NanoSIMS) was employed to detect trace sulphur distributions in commercial TBCs. After heat treatments, sulphur segregates at three typical areas in TBCs: (1) the yttria stabilized zirconia (YSZ) top coat; (2) the TGO/bond coat interface and (3) the grit blasted surface. This indicates that during heat treatment a significant outward diffusion of sulphur occurs from the superalloy to YSZ top coat through the TGO, and a possible mechanism for the migration of sulphur in TBCs is described. The undesired "sulphur effect" on scale adhesion was suggested to be caused by the formation of residual sulphides beneath the alumina scale with weaker ionic bonding to alloy cations. Possible solutions are suggested aiming to alleviate the sulphur effect in TBCs. | - |
dc.language | eng | - |
dc.relation.ispartof | Materials and Design | - |
dc.subject | Thermal barrier coatings (TBCs) | - |
dc.subject | Adhesion | - |
dc.subject | Oxidation | - |
dc.subject | Transmission electron microscopy (TEM) | - |
dc.subject | Second ion mass spectrometry (SIMS) | - |
dc.subject | Sulphur | - |
dc.title | Migration of sulphur in thermal barrier coatings during heat treatment | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/j.matdes.2016.02.109 | - |
dc.identifier.scopus | eid_2-s2.0-84961774568 | - |
dc.identifier.volume | 97 | - |
dc.identifier.spage | 364 | - |
dc.identifier.epage | 371 | - |
dc.identifier.eissn | 1873-4197 | - |
dc.identifier.isi | WOS:000372506500043 | - |