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Article: Mild, selective and switchable transfer reduction of nitroarenes catalyzed by supported gold nanoparticles

TitleMild, selective and switchable transfer reduction of nitroarenes catalyzed by supported gold nanoparticles
Authors
Issue Date2013
Citation
Catalysis Science and Technology, 2013, v. 3, n. 12, p. 3200-3206 How to Cite?
AbstractA highly versatile and flexible gold-based catalytic system has been developed for the controlled and selective transfer reduction of nitroarene using 2-propanol as a convenient hydrogen source under mild conditions. Depending on the specific reaction conditions, multiple products including azoxyarenes, symmetric or asymmetric azoarenes and anilines can be obtained respectively via a controlled reduction of the nitro aromatics with good to excellent yields in the presence of a reusable mesostructured ceria-supported gold (Au/meso-CeO2) catalyst. The overall operational simplicity, high chemoselectivity, functional-group tolerance and reusability of the catalyst make this approach an attractive and reliable tool for organic and process chemists. © The Royal Society of Chemistry.
Persistent Identifierhttp://hdl.handle.net/10722/299501
ISSN
2023 Impact Factor: 4.4
2023 SCImago Journal Rankings: 1.050
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLiu, Xiang-
dc.contributor.authorYe, Sen-
dc.contributor.authorLi, Hai Qian-
dc.contributor.authorLiu, Yong Mei-
dc.contributor.authorCao, Yong-
dc.contributor.authorFan, Kang Nian-
dc.date.accessioned2021-05-21T03:34:32Z-
dc.date.available2021-05-21T03:34:32Z-
dc.date.issued2013-
dc.identifier.citationCatalysis Science and Technology, 2013, v. 3, n. 12, p. 3200-3206-
dc.identifier.issn2044-4753-
dc.identifier.urihttp://hdl.handle.net/10722/299501-
dc.description.abstractA highly versatile and flexible gold-based catalytic system has been developed for the controlled and selective transfer reduction of nitroarene using 2-propanol as a convenient hydrogen source under mild conditions. Depending on the specific reaction conditions, multiple products including azoxyarenes, symmetric or asymmetric azoarenes and anilines can be obtained respectively via a controlled reduction of the nitro aromatics with good to excellent yields in the presence of a reusable mesostructured ceria-supported gold (Au/meso-CeO<inf>2</inf>) catalyst. The overall operational simplicity, high chemoselectivity, functional-group tolerance and reusability of the catalyst make this approach an attractive and reliable tool for organic and process chemists. © The Royal Society of Chemistry.-
dc.languageeng-
dc.relation.ispartofCatalysis Science and Technology-
dc.titleMild, selective and switchable transfer reduction of nitroarenes catalyzed by supported gold nanoparticles-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/c3cy00533j-
dc.identifier.scopuseid_2-s2.0-84888260183-
dc.identifier.volume3-
dc.identifier.issue12-
dc.identifier.spage3200-
dc.identifier.epage3206-
dc.identifier.eissn2044-4761-
dc.identifier.isiWOS:000326988700013-

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