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- Publisher Website: 10.1021/ma201689e
- Scopus: eid_2-s2.0-84255209185
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Article: Flexible electrochromic devices based on optoelectronically active polynorbornene layer and ultratransparent graphene electrodes
Title | Flexible electrochromic devices based on optoelectronically active polynorbornene layer and ultratransparent graphene electrodes |
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Authors | |
Issue Date | 2011 |
Citation | Macromolecules, 2011, v. 44, n. 24, p. 9550-9555 How to Cite? |
Abstract | Novel electrochromic polynorbornenes poly(NBPYTPAM) and poly(HNBPYTPAM), containing electroactive chromophores, were prepared via ring-opening metathesis polymerization (ROMP) from a new norbornene derivative (NBPYTPAM) using Grubbs' catalyst and followed by hydrogen reduction. The glass transition temperatures (T ) of poly(NBPYTPAM) and hydrogenated poly(HNBPYTPAM) were 190 and 175 °C, respectively. The cyclic voltammogram of the poly(HNBPYTPAM) film cast onto flexible graphene-coated polyethylene terephthalene (PET) substrates exhibited two reversible oxidation redox couples at 1.0 and 1.9 V. Flexible electrochromic devices were fabricated from the electroactive polymers and graphene-coated PET substrates. The electrochromic characteristics of poly(HNBPYTPAM) showed excellent stability and reversibility, with multistaged color changes from its yellow neutral form to green and then to dark-blue. © 2011 American Chemical Society. g |
Persistent Identifier | http://hdl.handle.net/10722/298547 |
ISSN | 2023 Impact Factor: 5.1 2023 SCImago Journal Rankings: 1.401 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Lian, Wei Ren | - |
dc.contributor.author | Huang, Ying Chi | - |
dc.contributor.author | Liao, Yi An | - |
dc.contributor.author | Wang, Kun Li | - |
dc.contributor.author | Li, Lain Jong | - |
dc.contributor.author | Su, Ching Yuan | - |
dc.contributor.author | Liaw, Der Jang | - |
dc.contributor.author | Lee, Kueir Rarn | - |
dc.contributor.author | Lai, Juin Yih | - |
dc.date.accessioned | 2021-04-08T03:08:44Z | - |
dc.date.available | 2021-04-08T03:08:44Z | - |
dc.date.issued | 2011 | - |
dc.identifier.citation | Macromolecules, 2011, v. 44, n. 24, p. 9550-9555 | - |
dc.identifier.issn | 0024-9297 | - |
dc.identifier.uri | http://hdl.handle.net/10722/298547 | - |
dc.description.abstract | Novel electrochromic polynorbornenes poly(NBPYTPAM) and poly(HNBPYTPAM), containing electroactive chromophores, were prepared via ring-opening metathesis polymerization (ROMP) from a new norbornene derivative (NBPYTPAM) using Grubbs' catalyst and followed by hydrogen reduction. The glass transition temperatures (T ) of poly(NBPYTPAM) and hydrogenated poly(HNBPYTPAM) were 190 and 175 °C, respectively. The cyclic voltammogram of the poly(HNBPYTPAM) film cast onto flexible graphene-coated polyethylene terephthalene (PET) substrates exhibited two reversible oxidation redox couples at 1.0 and 1.9 V. Flexible electrochromic devices were fabricated from the electroactive polymers and graphene-coated PET substrates. The electrochromic characteristics of poly(HNBPYTPAM) showed excellent stability and reversibility, with multistaged color changes from its yellow neutral form to green and then to dark-blue. © 2011 American Chemical Society. g | - |
dc.language | eng | - |
dc.relation.ispartof | Macromolecules | - |
dc.title | Flexible electrochromic devices based on optoelectronically active polynorbornene layer and ultratransparent graphene electrodes | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1021/ma201689e | - |
dc.identifier.scopus | eid_2-s2.0-84255209185 | - |
dc.identifier.volume | 44 | - |
dc.identifier.issue | 24 | - |
dc.identifier.spage | 9550 | - |
dc.identifier.epage | 9555 | - |
dc.identifier.isi | WOS:000298198600009 | - |
dc.identifier.issnl | 0024-9297 | - |