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Article: Efficient in situ three-component formation of chiral oxazoline-Schiff base copper(ii) complexes: Towards combinatorial library of chiral catalysts for asymmetric Henry reaction

TitleEfficient in situ three-component formation of chiral oxazoline-Schiff base copper(ii) complexes: Towards combinatorial library of chiral catalysts for asymmetric Henry reaction
Authors
Issue Date2010
Citation
Organic and Biomolecular Chemistry, 2010, v. 8, n. 13, p. 2956-2960 How to Cite?
AbstractA combinatorial in situ three-component chiral oxazoline-Schiff base copper(ii) complex catalyst formation method was developed. This simple combinatorial chiral catalyst approach provided a modular library of chiral oxazoline-Schiff base copper(ii) complex catalysts. The catalytic activity of these in situ generated catalysts can be rapidly and conveniently evaluated in the asymmetric Henry reaction. Moderate to good yields and enantioselectivities (up to 92% ee) were obtained under the optimized condition. The combination of modular three-component catalyst formation and in situ asymmetric reaction provides a new technology in asymmetric catalysis. © 2010 The Royal Society of Chemistry.
Persistent Identifierhttp://hdl.handle.net/10722/291969
ISSN
2023 Impact Factor: 2.9
2023 SCImago Journal Rankings: 0.607
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorYang, Wen-
dc.contributor.authorLiu, Han-
dc.contributor.authorDu, Da Ming-
dc.date.accessioned2020-11-17T14:55:29Z-
dc.date.available2020-11-17T14:55:29Z-
dc.date.issued2010-
dc.identifier.citationOrganic and Biomolecular Chemistry, 2010, v. 8, n. 13, p. 2956-2960-
dc.identifier.issn1477-0520-
dc.identifier.urihttp://hdl.handle.net/10722/291969-
dc.description.abstractA combinatorial in situ three-component chiral oxazoline-Schiff base copper(ii) complex catalyst formation method was developed. This simple combinatorial chiral catalyst approach provided a modular library of chiral oxazoline-Schiff base copper(ii) complex catalysts. The catalytic activity of these in situ generated catalysts can be rapidly and conveniently evaluated in the asymmetric Henry reaction. Moderate to good yields and enantioselectivities (up to 92% ee) were obtained under the optimized condition. The combination of modular three-component catalyst formation and in situ asymmetric reaction provides a new technology in asymmetric catalysis. © 2010 The Royal Society of Chemistry.-
dc.languageeng-
dc.relation.ispartofOrganic and Biomolecular Chemistry-
dc.titleEfficient in situ three-component formation of chiral oxazoline-Schiff base copper(ii) complexes: Towards combinatorial library of chiral catalysts for asymmetric Henry reaction-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/b923835b-
dc.identifier.pmid20458398-
dc.identifier.scopuseid_2-s2.0-77953745472-
dc.identifier.volume8-
dc.identifier.issue13-
dc.identifier.spage2956-
dc.identifier.epage2960-
dc.identifier.isiWOS:000278824700010-
dc.identifier.issnl1477-0520-

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