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Article: Effect of borane source on the enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones
Title | Effect of borane source on the enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones |
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Authors | |
Issue Date | 2007 |
Citation | Heteroatom Chemistry, 2007, v. 18, n. 7, p. 740-746 How to Cite? |
Abstract | The effect of borane source on enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones has been investigated by using (S)-3,1,2-oxazaborobicyclo[3.3.0]octane and (S)-7,3,1,2-thiaxazaborobicyclo[3.3.0]octane as catalysts. The results indicate that the enantioselective order of different borane sources is borane-dimethyl sulfide < borane-N,N-diethylaniline < borane-THF for the asymmetric reduction of a ketone under the same conditions. ©2007 Wiley Periodicals, Inc. |
Persistent Identifier | http://hdl.handle.net/10722/291796 |
ISSN | 2023 Impact Factor: 1.1 2023 SCImago Journal Rankings: 0.167 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Wang, Xiao | - |
dc.contributor.author | Du, Juanjuan | - |
dc.contributor.author | Liu, Han | - |
dc.contributor.author | Du, Da Ming | - |
dc.contributor.author | Xu, Jiaxi | - |
dc.date.accessioned | 2020-11-17T14:55:08Z | - |
dc.date.available | 2020-11-17T14:55:08Z | - |
dc.date.issued | 2007 | - |
dc.identifier.citation | Heteroatom Chemistry, 2007, v. 18, n. 7, p. 740-746 | - |
dc.identifier.issn | 1042-7163 | - |
dc.identifier.uri | http://hdl.handle.net/10722/291796 | - |
dc.description.abstract | The effect of borane source on enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones has been investigated by using (S)-3,1,2-oxazaborobicyclo[3.3.0]octane and (S)-7,3,1,2-thiaxazaborobicyclo[3.3.0]octane as catalysts. The results indicate that the enantioselective order of different borane sources is borane-dimethyl sulfide < borane-N,N-diethylaniline < borane-THF for the asymmetric reduction of a ketone under the same conditions. ©2007 Wiley Periodicals, Inc. | - |
dc.language | eng | - |
dc.relation.ispartof | Heteroatom Chemistry | - |
dc.title | Effect of borane source on the enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones | - |
dc.type | Article | - |
dc.description.nature | link_to_OA_fulltext | - |
dc.identifier.doi | 10.1002/hc.20370 | - |
dc.identifier.scopus | eid_2-s2.0-36448972776 | - |
dc.identifier.volume | 18 | - |
dc.identifier.issue | 7 | - |
dc.identifier.spage | 740 | - |
dc.identifier.epage | 746 | - |
dc.identifier.eissn | 1098-1071 | - |
dc.identifier.isi | WOS:000251367100005 | - |
dc.identifier.issnl | 1042-7163 | - |