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- Publisher Website: 10.1002/cphc.201900581
- Scopus: eid_2-s2.0-85068924830
- PMID: 31231907
- WOS: WOS:000474991600001
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Article: Excited State Dynamics of Isocyano Rhenium(I) Phenanthroline Complexes from Time‐Resolved Spectroscopy
Title | Excited State Dynamics of Isocyano Rhenium(I) Phenanthroline Complexes from Time‐Resolved Spectroscopy |
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Authors | |
Keywords | density functional calculations isocyanide ligands Raman spectroscopy rhenium time-resolved spectroscopy |
Issue Date | 2019 |
Publisher | Wiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.chemphyschem.com |
Citation | ChemPhysChem, 2019, v. 20 n. 15, p. 1946-1953 How to Cite? |
Abstract | The photophysical processes in a series of isocyano Re(I) phenanthroline complexes {[Re(CNR)n(CO)4‐n(phen)](PF6); n=2, 3, 4, R=2,6‐(iPr)2C6H3‐ or tBu‐ (n=2)} in acetonitrile have been studied by resonance Raman spectroscopy, transient resonance Raman spectroscopy, and femtosecond / nanosecond transient spectroscopy to elucidate the nature of their electronic transitions and emissive excited state(s). The kinetics of the intersystem crossing, vibrational relaxation and radiative decay of the metal‐to‐ligand charge transfer {MLCT [dπ(Re)→π*(phen)]} excited state have also been determined. |
Persistent Identifier | http://hdl.handle.net/10722/286178 |
ISSN | 2023 Impact Factor: 2.3 2023 SCImago Journal Rankings: 0.623 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Cheng, SC | - |
dc.contributor.author | Chu, WK | - |
dc.contributor.author | Ko, CC | - |
dc.contributor.author | Phillips, DL | - |
dc.date.accessioned | 2020-08-31T07:00:14Z | - |
dc.date.available | 2020-08-31T07:00:14Z | - |
dc.date.issued | 2019 | - |
dc.identifier.citation | ChemPhysChem, 2019, v. 20 n. 15, p. 1946-1953 | - |
dc.identifier.issn | 1439-4235 | - |
dc.identifier.uri | http://hdl.handle.net/10722/286178 | - |
dc.description.abstract | The photophysical processes in a series of isocyano Re(I) phenanthroline complexes {[Re(CNR)n(CO)4‐n(phen)](PF6); n=2, 3, 4, R=2,6‐(iPr)2C6H3‐ or tBu‐ (n=2)} in acetonitrile have been studied by resonance Raman spectroscopy, transient resonance Raman spectroscopy, and femtosecond / nanosecond transient spectroscopy to elucidate the nature of their electronic transitions and emissive excited state(s). The kinetics of the intersystem crossing, vibrational relaxation and radiative decay of the metal‐to‐ligand charge transfer {MLCT [dπ(Re)→π*(phen)]} excited state have also been determined. | - |
dc.language | eng | - |
dc.publisher | Wiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.chemphyschem.com | - |
dc.relation.ispartof | ChemPhysChem | - |
dc.rights | This is the peer reviewed version of the following article: [FULL CITE], which has been published in final form at [Link to final article using the DOI]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | - |
dc.subject | density functional calculations | - |
dc.subject | isocyanide ligands | - |
dc.subject | Raman spectroscopy | - |
dc.subject | rhenium | - |
dc.subject | time-resolved spectroscopy | - |
dc.title | Excited State Dynamics of Isocyano Rhenium(I) Phenanthroline Complexes from Time‐Resolved Spectroscopy | - |
dc.type | Article | - |
dc.identifier.email | Phillips, DL: phillips@hku.hk | - |
dc.identifier.authority | Phillips, DL=rp00770 | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1002/cphc.201900581 | - |
dc.identifier.pmid | 31231907 | - |
dc.identifier.scopus | eid_2-s2.0-85068924830 | - |
dc.identifier.hkuros | 313840 | - |
dc.identifier.volume | 20 | - |
dc.identifier.issue | 15 | - |
dc.identifier.spage | 1946 | - |
dc.identifier.epage | 1953 | - |
dc.identifier.isi | WOS:000474991600001 | - |
dc.publisher.place | Germany | - |
dc.identifier.issnl | 1439-4235 | - |