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Article: Luminescent Tungsten(vi) Complexes As Photocatalysts For Light-driven C–c And C–b Bond Formation Reactions

TitleLuminescent Tungsten(vi) Complexes As Photocatalysts For Light-driven C–c And C–b Bond Formation Reactions
Authors
Yu, DTo, WPTong, GSMWu, LLChan, KTDu, LPhillips, DLLiu, YChe, CM
KeywordsChemical bonds
Chlorine compounds
Light
Photochemical reactions
Redox reactions
Issue Date2020
PublisherRoyal Society of Chemistry: Open Access. The Journal's web site is located at http://www.rsc.org/publishing/journals/sc/About.asp
Citation
Chemical Science, 2020, v. 11 n. 25, p. 6370-6382 How to Cite?
DOI: http://dx.doi.org/10.1039/D0SC01340D
AbstractThe realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-lightabsorbing photoluminescent tungsten(VI) complex which can be conveniently prepared at the gramscale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C–C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance.
Persistent Identifierhttp://hdl.handle.net/10722/286160
ISSN
2041-6520
2023 Impact Factor: 7.6
2023 SCImago Journal Rankings: 2.333
PubMed Central ID
PMC7448528
ISI Accession Number ID
WOS:000544484900023

 

DC FieldValueLanguage
dc.contributor.authorYu, D-
dc.contributor.authorTo, WP-
dc.contributor.authorTong, GSM-
dc.contributor.authorWu, LL-
dc.contributor.authorChan, KT-
dc.contributor.authorDu, L-
dc.contributor.authorPhillips, DL-
dc.contributor.authorLiu, Y-
dc.contributor.authorChe, CM-
dc.date.accessioned2020-08-31T06:59:58Z-
dc.date.available2020-08-31T06:59:58Z-
dc.date.issued2020-
dc.identifier.citationChemical Science, 2020, v. 11 n. 25, p. 6370-6382-
dc.identifier.issn2041-6520-
dc.identifier.urihttp://hdl.handle.net/10722/286160-
dc.description.abstractThe realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-lightabsorbing photoluminescent tungsten(VI) complex which can be conveniently prepared at the gramscale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C–C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance.-
dc.languageeng-
dc.publisherRoyal Society of Chemistry: Open Access. The Journal's web site is located at http://www.rsc.org/publishing/journals/sc/About.asp-
dc.relation.ispartofChemical Science-
dc.rightsThis work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.-
dc.subjectChemical bonds-
dc.subjectChlorine compounds-
dc.subjectLight-
dc.subjectPhotochemical reactions-
dc.subjectRedox reactions-
dc.titleLuminescent Tungsten(vi) Complexes As Photocatalysts For Light-driven C–c And C–b Bond Formation Reactions-
dc.typeArticle-
dc.identifier.emailYu, D: yudh123@hku.hk-
dc.identifier.emailTo, WP: kevintwp@hku.hk-
dc.identifier.emailTong, GSM: tongsm@hku.hk-
dc.identifier.emailWu, LL: llwusx@hku.hk-
dc.identifier.emailDu, L: ailleen@hku.hk-
dc.identifier.emailPhillips, DL: phillips@hku.hk-
dc.identifier.emailChe, CM: chemhead@hku.hk-
dc.identifier.authorityTo, WP=rp02410-
dc.identifier.authorityTong, GSM=rp00790-
dc.identifier.authorityPhillips, DL=rp00770-
dc.identifier.authorityChe, CM=rp00670-
dc.description.naturepublished_or_final_version-
dc.identifier.doi10.1039/D0SC01340D-
dc.identifier.pmid32874518-
dc.identifier.pmcidPMC7448528-
dc.identifier.scopuseid_2-s2.0-85087781901-
dc.identifier.hkuros313156-
dc.identifier.volume11-
dc.identifier.issue25-
dc.identifier.spage6370-
dc.identifier.epage6382-
dc.identifier.isiWOS:000544484900023-
dc.publisher.placeUnited Kingdom-
dc.identifier.issnl2041-6520-

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