File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Influence of Donor Polymer on the Molecular Ordering of Small Molecular Acceptors in Nonfullerene Polymer Solar Cells

TitleInfluence of Donor Polymer on the Molecular Ordering of Small Molecular Acceptors in Nonfullerene Polymer Solar Cells
Authors
Keywordsmorphology
coherence length
polymer solar cells
X-ray scattering
small molecular acceptor
Issue Date2018
Citation
Advanced Energy Materials, 2018, v. 8, n. 5, article no. 1701674 How to Cite?
Abstract© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Nonfullerene polymer solar cells (PSCs) based on polymer donors and nonfullerene small molecular acceptors (SMAs) have recently attracted considerable attention. Although much of the progress is driven by the development of novel SMAs, the donor polymer also plays an important role in achieving efficient nonfullerene PSCs. However, it is far from clear how the polymer donor choice influences the morphology and performance of the SMAs and the nonfullerene blends. In addition, it is challenging to carry out quantitative analysis of the morphology of polymer:SMA blends, due to the low material contrast and overlapping scattering features of the π–π stacking between the two organic components. Here, a series of nonfullerene blends is studied based on ITIC-Th blended with five different donor polymers. Through quantitative morphology analysis, the (010) coherence length of the SMA is characterized and a positive correlation between the coherence length of the SMA and the device fill factor (FF) is established. The study reveals that the donor polymer can significantly change the molecular ordering of the SMA and thus improve the electron mobility and domain purity of the blend, which has an overall positive effect that leads to the enhanced device FF for nonfullerene PSCs.
Persistent Identifierhttp://hdl.handle.net/10722/285804
ISSN
2023 Impact Factor: 24.4
2023 SCImago Journal Rankings: 8.748
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorHu, Huawei-
dc.contributor.authorJiang, Kui-
dc.contributor.authorChow, Philip C.Y.-
dc.contributor.authorYe, Long-
dc.contributor.authorZhang, Guangye-
dc.contributor.authorLi, Zhengke-
dc.contributor.authorCarpenter, Joshua H.-
dc.contributor.authorAde, Harald-
dc.contributor.authorYan, He-
dc.date.accessioned2020-08-18T04:56:41Z-
dc.date.available2020-08-18T04:56:41Z-
dc.date.issued2018-
dc.identifier.citationAdvanced Energy Materials, 2018, v. 8, n. 5, article no. 1701674-
dc.identifier.issn1614-6832-
dc.identifier.urihttp://hdl.handle.net/10722/285804-
dc.description.abstract© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Nonfullerene polymer solar cells (PSCs) based on polymer donors and nonfullerene small molecular acceptors (SMAs) have recently attracted considerable attention. Although much of the progress is driven by the development of novel SMAs, the donor polymer also plays an important role in achieving efficient nonfullerene PSCs. However, it is far from clear how the polymer donor choice influences the morphology and performance of the SMAs and the nonfullerene blends. In addition, it is challenging to carry out quantitative analysis of the morphology of polymer:SMA blends, due to the low material contrast and overlapping scattering features of the π–π stacking between the two organic components. Here, a series of nonfullerene blends is studied based on ITIC-Th blended with five different donor polymers. Through quantitative morphology analysis, the (010) coherence length of the SMA is characterized and a positive correlation between the coherence length of the SMA and the device fill factor (FF) is established. The study reveals that the donor polymer can significantly change the molecular ordering of the SMA and thus improve the electron mobility and domain purity of the blend, which has an overall positive effect that leads to the enhanced device FF for nonfullerene PSCs.-
dc.languageeng-
dc.relation.ispartofAdvanced Energy Materials-
dc.subjectmorphology-
dc.subjectcoherence length-
dc.subjectpolymer solar cells-
dc.subjectX-ray scattering-
dc.subjectsmall molecular acceptor-
dc.titleInfluence of Donor Polymer on the Molecular Ordering of Small Molecular Acceptors in Nonfullerene Polymer Solar Cells-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/aenm.201701674-
dc.identifier.scopuseid_2-s2.0-85042088938-
dc.identifier.volume8-
dc.identifier.issue5-
dc.identifier.spagearticle no. 1701674-
dc.identifier.epagearticle no. 1701674-
dc.identifier.eissn1614-6840-
dc.identifier.isiWOS:000425113600011-
dc.identifier.issnl1614-6832-

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats