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Article: Thermally Stimulated Delayed Phosphorescence (TSDP)-Based Gold(III) Complexes of Tridentate Pyrazine-Containing Pincer Ligand with Wide Emission Color Tunability and Their Application in Organic Light-Emitting Devices

TitleThermally Stimulated Delayed Phosphorescence (TSDP)-Based Gold(III) Complexes of Tridentate Pyrazine-Containing Pincer Ligand with Wide Emission Color Tunability and Their Application in Organic Light-Emitting Devices
Authors
Issue Date2020
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html
Citation
Journal of the American Chemical Society, 2020, v. 142 n. 5, p. 2448-2459 How to Cite?
AbstractA new class of pyrazine-based carbazole-containing gold(III) complexes featuring thermally stimulated delayed phosphorescence (TSDP) properties has been designed and synthesized. The emission colors are found to be sensitive to the coordinating atom of the carbazolyl ligands at the gold(III) center, with emission energies spanning from green to red. The efficiency of TSDP can be enhanced by lowering the polarity of the solvent, as supported by the variable-temperature emission and computational studies. Interestingly, a significant spectral shift in electroluminescence with the change of Commission Internationale de L’Eclairage (CIE) coordinates from (0.35, 0.60) to (0.44, 0.54) has been achieved by simply changing the host material from CBP to TmPyPB. Solution-processable organic light-emitting devices (OLEDs) have also been fabricated, with maximum current efficiencies of up to 22.4 cd A–1 and maximum external quantum efficiencies (EQEs) approaching 7.0%. A higher current efficiency of 35.1 cd A–1 and EQE of 10.7% can be achieved for the vacuum-deposited device based on 1, representing the first demonstration of pyrazine-based tridentate ligand-containing gold(III) complexes as phosphorescent material for OLED application.
Persistent Identifierhttp://hdl.handle.net/10722/285443
ISSN
2023 Impact Factor: 14.4
2023 SCImago Journal Rankings: 5.489
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLeung, MY-
dc.contributor.authorTang, MC-
dc.contributor.authorCheung, WL-
dc.contributor.authorLai, SL-
dc.contributor.authorNg, M-
dc.contributor.authorChan, MY-
dc.contributor.authorYam, VWW-
dc.date.accessioned2020-08-18T03:53:28Z-
dc.date.available2020-08-18T03:53:28Z-
dc.date.issued2020-
dc.identifier.citationJournal of the American Chemical Society, 2020, v. 142 n. 5, p. 2448-2459-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/285443-
dc.description.abstractA new class of pyrazine-based carbazole-containing gold(III) complexes featuring thermally stimulated delayed phosphorescence (TSDP) properties has been designed and synthesized. The emission colors are found to be sensitive to the coordinating atom of the carbazolyl ligands at the gold(III) center, with emission energies spanning from green to red. The efficiency of TSDP can be enhanced by lowering the polarity of the solvent, as supported by the variable-temperature emission and computational studies. Interestingly, a significant spectral shift in electroluminescence with the change of Commission Internationale de L’Eclairage (CIE) coordinates from (0.35, 0.60) to (0.44, 0.54) has been achieved by simply changing the host material from CBP to TmPyPB. Solution-processable organic light-emitting devices (OLEDs) have also been fabricated, with maximum current efficiencies of up to 22.4 cd A–1 and maximum external quantum efficiencies (EQEs) approaching 7.0%. A higher current efficiency of 35.1 cd A–1 and EQE of 10.7% can be achieved for the vacuum-deposited device based on 1, representing the first demonstration of pyrazine-based tridentate ligand-containing gold(III) complexes as phosphorescent material for OLED application.-
dc.languageeng-
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titleThermally Stimulated Delayed Phosphorescence (TSDP)-Based Gold(III) Complexes of Tridentate Pyrazine-Containing Pincer Ligand with Wide Emission Color Tunability and Their Application in Organic Light-Emitting Devices-
dc.typeArticle-
dc.identifier.emailTang, MC: kobetang@hku.hk-
dc.identifier.emailLai, SL: slllai@hku.hk-
dc.identifier.emailNg, M: mkyng@hku.hk-
dc.identifier.emailChan, MY: chanmym@hku.hk-
dc.identifier.emailYam, VWW: wwyam@hku.hk-
dc.identifier.authorityChan, MY=rp00666-
dc.identifier.authorityYam, VWW=rp00822-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/jacs.9b12136-
dc.identifier.pmid31927952-
dc.identifier.scopuseid_2-s2.0-85078331941-
dc.identifier.hkuros313049-
dc.identifier.volume142-
dc.identifier.issue5-
dc.identifier.spage2448-
dc.identifier.epage2459-
dc.identifier.isiWOS:000512222700051-
dc.publisher.placeUnited States-
dc.identifier.issnl0002-7863-

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