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Conference Paper: From Simple Discrete Metal Complexes to Supramolecular Assemblies and Structures
Title | From Simple Discrete Metal Complexes to Supramolecular Assemblies and Structures |
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Authors | |
Issue Date | 2013 |
Publisher | University of Cincinnati. |
Citation | 2013 Oesper Symposium in honor of Rich Eisenberg, University of Cincinnati, Cincinnati, USA, 24-25 October 2013 How to Cite? |
Abstract | Recent works in our laboratory have shown that novel classes of photo functional metalcontaining molecular materials could be assembled through the use of various metal-ligand
chromophoric coordination motifs and building blocks. In this presentation, various design and
synthetic strategies will be described. A number of these complexes have been shown to display
rich optical and luminescence behavior. The optical and luminescence properties have been
studied and their origins elucidated. Correlations of the optical and luminescence behavior with
the electronic and structural effects of the metal complexes have also been made. These simple
discrete metal complexes have also been shown to undergo assembly to give a variety of
supramolecular assemblies, nanostructures and morphologies. By understanding the
spectroscopic origin and the structure-property relationships, the characteristics of these metal
complexes could be fine-tuned for specific applications and functions through rational design
and assembly strategies based on the fine interplay of electrostatics and supramolecular noncovalent metal-metal and π-π interactions. These metal-ligand chromophoric complexes may
find potential applications and functions as efficient triplet emitters and as luminescence
materials for chemosensing, biological assays and molecular imaging. |
Description | Invited Lecture |
Persistent Identifier | http://hdl.handle.net/10722/285196 |
DC Field | Value | Language |
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dc.contributor.author | Yam, VWW | - |
dc.date.accessioned | 2020-08-14T02:54:56Z | - |
dc.date.available | 2020-08-14T02:54:56Z | - |
dc.date.issued | 2013 | - |
dc.identifier.citation | 2013 Oesper Symposium in honor of Rich Eisenberg, University of Cincinnati, Cincinnati, USA, 24-25 October 2013 | - |
dc.identifier.uri | http://hdl.handle.net/10722/285196 | - |
dc.description | Invited Lecture | - |
dc.description.abstract | Recent works in our laboratory have shown that novel classes of photo functional metalcontaining molecular materials could be assembled through the use of various metal-ligand chromophoric coordination motifs and building blocks. In this presentation, various design and synthetic strategies will be described. A number of these complexes have been shown to display rich optical and luminescence behavior. The optical and luminescence properties have been studied and their origins elucidated. Correlations of the optical and luminescence behavior with the electronic and structural effects of the metal complexes have also been made. These simple discrete metal complexes have also been shown to undergo assembly to give a variety of supramolecular assemblies, nanostructures and morphologies. By understanding the spectroscopic origin and the structure-property relationships, the characteristics of these metal complexes could be fine-tuned for specific applications and functions through rational design and assembly strategies based on the fine interplay of electrostatics and supramolecular noncovalent metal-metal and π-π interactions. These metal-ligand chromophoric complexes may find potential applications and functions as efficient triplet emitters and as luminescence materials for chemosensing, biological assays and molecular imaging. | - |
dc.language | eng | - |
dc.publisher | University of Cincinnati. | - |
dc.relation.ispartof | 2013 Oesper Symposium in honor of Rich Eisenberg, University of Cincinnati | - |
dc.title | From Simple Discrete Metal Complexes to Supramolecular Assemblies and Structures | - |
dc.type | Conference_Paper | - |
dc.identifier.email | Yam, VWW: wwyam@hku.hk | - |
dc.identifier.authority | Yam, VWW=rp00822 | - |
dc.identifier.hkuros | 239420 | - |
dc.publisher.place | Cincinnati, USA | - |