File Download
There are no files associated with this item.
Supplementary
-
Citations:
- Appears in Collections:
Conference Paper: From Simple Discrete Metal Complexes to Supramolecular Assembly and Nanostructures
Title | From Simple Discrete Metal Complexes to Supramolecular Assembly and Nanostructures |
---|---|
Authors | |
Issue Date | 2016 |
Citation | 2016 Lavoisier Lectureship, University of Paris Diderot 7, France, 20-25 November 2016 How to Cite? |
Abstract | Recent works in our laboratory have shown that novel classes of light-absorbing and luminescent
metal-containing molecular materials could be assembled through the use of various metal-ligand
chromophoric building blocks. In this presentation, various design and synthetic strategies will be
described. A number of these metal-ligand chromophoric complexes have been shown to display rich
optical and luminescence behavior. Correlations of the chromophoric and luminescence behavior with
the electronic and structural effects of the metal complexes have been made to elucidate their
spectroscopic origins. These simple discrete metal complexes are found to undergo supramolecular
assembly to give a variety of nanostructures and morphologies. By understanding the spectroscopic
origin and the structure-property relationships, different approaches and assembly motifs have been
employed to tune their electronic absorption and emission characteristics. Subtle changes in the
microenvironment and nanostructured morphologies have led to drastic changes in both the electronic
absorption and emission properties of these supramolecular assemblies. Explorations into the
underlying factors that determine their spectroscopic properties and morphologies as well as their
assembly mechanisms have provided new insights into the understanding of the interplay of the
various intermolecular forces and interactions for the directed assembly of novel classes of metalcontaining soft materials and hybrids. |
Description | Award Lecture |
Persistent Identifier | http://hdl.handle.net/10722/285186 |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yam, VWW | - |
dc.date.accessioned | 2020-08-13T04:15:39Z | - |
dc.date.available | 2020-08-13T04:15:39Z | - |
dc.date.issued | 2016 | - |
dc.identifier.citation | 2016 Lavoisier Lectureship, University of Paris Diderot 7, France, 20-25 November 2016 | - |
dc.identifier.uri | http://hdl.handle.net/10722/285186 | - |
dc.description | Award Lecture | - |
dc.description.abstract | Recent works in our laboratory have shown that novel classes of light-absorbing and luminescent metal-containing molecular materials could be assembled through the use of various metal-ligand chromophoric building blocks. In this presentation, various design and synthetic strategies will be described. A number of these metal-ligand chromophoric complexes have been shown to display rich optical and luminescence behavior. Correlations of the chromophoric and luminescence behavior with the electronic and structural effects of the metal complexes have been made to elucidate their spectroscopic origins. These simple discrete metal complexes are found to undergo supramolecular assembly to give a variety of nanostructures and morphologies. By understanding the spectroscopic origin and the structure-property relationships, different approaches and assembly motifs have been employed to tune their electronic absorption and emission characteristics. Subtle changes in the microenvironment and nanostructured morphologies have led to drastic changes in both the electronic absorption and emission properties of these supramolecular assemblies. Explorations into the underlying factors that determine their spectroscopic properties and morphologies as well as their assembly mechanisms have provided new insights into the understanding of the interplay of the various intermolecular forces and interactions for the directed assembly of novel classes of metalcontaining soft materials and hybrids. | - |
dc.language | eng | - |
dc.relation.ispartof | Lavoisier Lectureship, University of Paris Diderot 7 | - |
dc.title | From Simple Discrete Metal Complexes to Supramolecular Assembly and Nanostructures | - |
dc.type | Conference_Paper | - |
dc.identifier.email | Yam, VWW: wwyam@hku.hk | - |
dc.identifier.authority | Yam, VWW=rp00822 | - |
dc.identifier.hkuros | 275395 | - |