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Article: Bottom-Up Synthesis of Nitrogen-Doped Polycyclic Aromatic Hydrocarbons

TitleBottom-Up Synthesis of Nitrogen-Doped Polycyclic Aromatic Hydrocarbons
Authors
Keywordspolycyclic aromatic hydrocarbons
nanographenes
heteroatoms
nitrogen doping
boron doping
Issue Date2020
PublisherThieme Publishing. The Journal's web site is located at http://www.thieme-chemistry.com/thieme-chemistry/journals/info/synlett/index.shtml
Citation
Synlett, 2020, v. 31 n. 3, p. 211-222 How to Cite?
AbstractBottom-up organic synthesis serves as an efficient method to provide atomically precise heteroatom-doped polycyclic aromatic hydrocarbons (PAHs) with not only well-defined size and edge structures but also specific concentrations and positions of the heteroatoms. We provide a plenary account of the preparation of nitrogen-doped PAHs (N-PAHs) through 1,3-dipolar cycloaddition between different dipolarophiles, as well as pyrazine-type N-doped diaza-hexa-peri-hexabenzocoronene (diaza-HBC). Additionally, we present the synthesis of a class of helical N-charged PAHs, including one charged aza[5]helicene and two charged aza[4]helicenes. Moreover, the bottom-up organic synthesis strategy is further extended to the construction of novel nitrogen-boron-nitrogen (NBN)-containing PAHs. Finally, we discuss the synthesis of four-coordinate boron chromophores containing 6,12,18-tris(alkyl amine)-5,11,17-triazatrinaphthylene derivative ligands.
Persistent Identifierhttp://hdl.handle.net/10722/284527
ISSN
2023 Impact Factor: 1.7
2023 SCImago Journal Rankings: 0.450
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLiu, J-
dc.contributor.authorFeng, X-
dc.date.accessioned2020-08-07T08:58:55Z-
dc.date.available2020-08-07T08:58:55Z-
dc.date.issued2020-
dc.identifier.citationSynlett, 2020, v. 31 n. 3, p. 211-222-
dc.identifier.issn0936-5214-
dc.identifier.urihttp://hdl.handle.net/10722/284527-
dc.description.abstractBottom-up organic synthesis serves as an efficient method to provide atomically precise heteroatom-doped polycyclic aromatic hydrocarbons (PAHs) with not only well-defined size and edge structures but also specific concentrations and positions of the heteroatoms. We provide a plenary account of the preparation of nitrogen-doped PAHs (N-PAHs) through 1,3-dipolar cycloaddition between different dipolarophiles, as well as pyrazine-type N-doped diaza-hexa-peri-hexabenzocoronene (diaza-HBC). Additionally, we present the synthesis of a class of helical N-charged PAHs, including one charged aza[5]helicene and two charged aza[4]helicenes. Moreover, the bottom-up organic synthesis strategy is further extended to the construction of novel nitrogen-boron-nitrogen (NBN)-containing PAHs. Finally, we discuss the synthesis of four-coordinate boron chromophores containing 6,12,18-tris(alkyl amine)-5,11,17-triazatrinaphthylene derivative ligands.-
dc.languageeng-
dc.publisherThieme Publishing. The Journal's web site is located at http://www.thieme-chemistry.com/thieme-chemistry/journals/info/synlett/index.shtml-
dc.relation.ispartofSynlett-
dc.rightsSynlett. Copyright © Thieme Publishing.-
dc.subjectpolycyclic aromatic hydrocarbons-
dc.subjectnanographenes-
dc.subjectheteroatoms-
dc.subjectnitrogen doping-
dc.subjectboron doping-
dc.titleBottom-Up Synthesis of Nitrogen-Doped Polycyclic Aromatic Hydrocarbons-
dc.typeArticle-
dc.identifier.emailLiu, J: juliu@hku.hk-
dc.identifier.authorityLiu, J=rp02584-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1055/s-0039-1690767-
dc.identifier.scopuseid_2-s2.0-85079392639-
dc.identifier.hkuros311680-
dc.identifier.volume31-
dc.identifier.issue3-
dc.identifier.spage211-
dc.identifier.epage222-
dc.identifier.isiWOS:000509900900003-
dc.publisher.placeGermany-
dc.identifier.issnl0936-5214-

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