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- Publisher Website: 10.1002/chem.201905647
- Scopus: eid_2-s2.0-85082939660
- PMID: 32022324
- WOS: WOS:000521631000001
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Article: Transition‐Metal‐Catalyzed Regioselective Functionalization of Monophosphino‐o‐ Carboranes
Title | Transition‐Metal‐Catalyzed Regioselective Functionalization of Monophosphino‐o‐ Carboranes |
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Authors | |
Keywords | alkylation arylation B−H activation carboranes halogenation |
Issue Date | 2020 |
Publisher | Wiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistry |
Citation | Chemistry - A European Journal, 2020, v. 26 n. 22, p. 5037-5050 How to Cite? |
Abstract | A facile approach to the synthesis of diaryl‐ and dialkyl‐substituted monophosphino‐o‐ carboranes by rhodium(I)‐catalyzed phosphine‐directed B3,6−H activation has been developed for the first time. Upon switching rhodium(I) to palladium(II), C ‐arylated and B 6‐halogenated products were obtained by using t BuOLi and Li2CO3 as base, respectively. These discoveries provide some simple and efficient approaches to the modification of monophosphino‐o‐ carboranes. |
Persistent Identifier | http://hdl.handle.net/10722/282892 |
ISSN | 2023 Impact Factor: 3.9 2023 SCImago Journal Rankings: 1.058 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Zhang, ZY | - |
dc.contributor.author | Zhang, X | - |
dc.contributor.author | Yuan, J | - |
dc.contributor.author | Yue, CD | - |
dc.contributor.author | Meng, S | - |
dc.contributor.author | Chen, J | - |
dc.contributor.author | Yu, GA | - |
dc.contributor.author | Che, CM | - |
dc.date.accessioned | 2020-06-05T06:22:47Z | - |
dc.date.available | 2020-06-05T06:22:47Z | - |
dc.date.issued | 2020 | - |
dc.identifier.citation | Chemistry - A European Journal, 2020, v. 26 n. 22, p. 5037-5050 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | http://hdl.handle.net/10722/282892 | - |
dc.description.abstract | A facile approach to the synthesis of diaryl‐ and dialkyl‐substituted monophosphino‐o‐ carboranes by rhodium(I)‐catalyzed phosphine‐directed B3,6−H activation has been developed for the first time. Upon switching rhodium(I) to palladium(II), C ‐arylated and B 6‐halogenated products were obtained by using t BuOLi and Li2CO3 as base, respectively. These discoveries provide some simple and efficient approaches to the modification of monophosphino‐o‐ carboranes. | - |
dc.language | eng | - |
dc.publisher | Wiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistry | - |
dc.relation.ispartof | Chemistry - A European Journal | - |
dc.rights | This is the peer reviewed version of the following article: [FULL CITE], which has been published in final form at [Link to final article using the DOI]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | - |
dc.subject | alkylation | - |
dc.subject | arylation | - |
dc.subject | B−H activation | - |
dc.subject | carboranes | - |
dc.subject | halogenation | - |
dc.title | Transition‐Metal‐Catalyzed Regioselective Functionalization of Monophosphino‐o‐ Carboranes | - |
dc.type | Article | - |
dc.identifier.email | Che, CM: chemhead@hku.hk | - |
dc.identifier.authority | Che, CM=rp00670 | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1002/chem.201905647 | - |
dc.identifier.pmid | 32022324 | - |
dc.identifier.scopus | eid_2-s2.0-85082939660 | - |
dc.identifier.hkuros | 310319 | - |
dc.identifier.volume | 26 | - |
dc.identifier.issue | 22 | - |
dc.identifier.spage | 5037 | - |
dc.identifier.epage | 5050 | - |
dc.identifier.isi | WOS:000521631000001 | - |
dc.publisher.place | Germany | - |
dc.identifier.issnl | 0947-6539 | - |