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Article: Transition‐Metal‐Catalyzed Regioselective Functionalization of Monophosphino‐o‐ Carboranes

TitleTransition‐Metal‐Catalyzed Regioselective Functionalization of Monophosphino‐o‐ Carboranes
Authors
Keywordsalkylation
arylation
B−H activation
carboranes
halogenation
Issue Date2020
PublisherWiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistry
Citation
Chemistry - A European Journal, 2020, v. 26 n. 22, p. 5037-5050 How to Cite?
AbstractA facile approach to the synthesis of diaryl‐ and dialkyl‐substituted monophosphino‐o‐ carboranes by rhodium(I)‐catalyzed phosphine‐directed B3,6−H activation has been developed for the first time. Upon switching rhodium(I) to palladium(II), C ‐arylated and B 6‐halogenated products were obtained by using t BuOLi and Li2CO3 as base, respectively. These discoveries provide some simple and efficient approaches to the modification of monophosphino‐o‐ carboranes.
Persistent Identifierhttp://hdl.handle.net/10722/282892
ISSN
2020 Impact Factor: 5.236
2015 SCImago Journal Rankings: 2.323
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorZhang, ZY-
dc.contributor.authorZhang, X-
dc.contributor.authorYuan, J-
dc.contributor.authorYue, CD-
dc.contributor.authorMeng, S-
dc.contributor.authorChen, J-
dc.contributor.authorYu, GA-
dc.contributor.authorChe, CM-
dc.date.accessioned2020-06-05T06:22:47Z-
dc.date.available2020-06-05T06:22:47Z-
dc.date.issued2020-
dc.identifier.citationChemistry - A European Journal, 2020, v. 26 n. 22, p. 5037-5050-
dc.identifier.issn0947-6539-
dc.identifier.urihttp://hdl.handle.net/10722/282892-
dc.description.abstractA facile approach to the synthesis of diaryl‐ and dialkyl‐substituted monophosphino‐o‐ carboranes by rhodium(I)‐catalyzed phosphine‐directed B3,6−H activation has been developed for the first time. Upon switching rhodium(I) to palladium(II), C ‐arylated and B 6‐halogenated products were obtained by using t BuOLi and Li2CO3 as base, respectively. These discoveries provide some simple and efficient approaches to the modification of monophosphino‐o‐ carboranes.-
dc.languageeng-
dc.publisherWiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistry-
dc.relation.ispartofChemistry - A European Journal-
dc.rightsThis is the peer reviewed version of the following article: [FULL CITE], which has been published in final form at [Link to final article using the DOI]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.-
dc.subjectalkylation-
dc.subjectarylation-
dc.subjectB−H activation-
dc.subjectcarboranes-
dc.subjecthalogenation-
dc.titleTransition‐Metal‐Catalyzed Regioselective Functionalization of Monophosphino‐o‐ Carboranes-
dc.typeArticle-
dc.identifier.emailChe, CM: chemhead@hku.hk-
dc.identifier.authorityChe, CM=rp00670-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/chem.201905647-
dc.identifier.pmid32022324-
dc.identifier.scopuseid_2-s2.0-85082939660-
dc.identifier.hkuros310319-
dc.identifier.volume26-
dc.identifier.issue22-
dc.identifier.spage5037-
dc.identifier.epage5050-
dc.identifier.isiWOS:000521631000001-
dc.publisher.placeGermany-
dc.identifier.issnl0947-6539-

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