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Conference Paper: Applications of Epoxy and Aziridinyl Enolsilanes in Intramolecular (4+3) and (3+2) Cycloadditions
Title | Applications of Epoxy and Aziridinyl Enolsilanes in Intramolecular (4+3) and (3+2) Cycloadditions |
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Authors | |
Issue Date | 2019 |
Citation | 102nd Canadian Chemistry Conference and Exhibition, Quebec City, Canada, 3-7 June 2019 How to Cite? |
Abstract | Epoxy and aziridinyl enolsilanes react as dienophiles in intramolecular (4+3) cycloadditions with typically challenging dienes such as pyrroles, thiophenes and benzenes. They also react as enophiles in intramolecular (3+2) reactions with dienes and alkenes. The reactions proceed through activated epoxides and aziridines as intermediates and therefore the cycloadducts can be obtained with high ee. |
Description | Oral Session - Part of: (OR Division) - A Symposium in Honour of Mark Lautens’ 60th Birthday |
Persistent Identifier | http://hdl.handle.net/10722/282732 |
DC Field | Value | Language |
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dc.contributor.author | Chiu, P | - |
dc.contributor.author | Zheng, Y | - |
dc.contributor.author | Chen, Y | - |
dc.date.accessioned | 2020-06-01T06:40:39Z | - |
dc.date.available | 2020-06-01T06:40:39Z | - |
dc.date.issued | 2019 | - |
dc.identifier.citation | 102nd Canadian Chemistry Conference and Exhibition, Quebec City, Canada, 3-7 June 2019 | - |
dc.identifier.uri | http://hdl.handle.net/10722/282732 | - |
dc.description | Oral Session - Part of: (OR Division) - A Symposium in Honour of Mark Lautens’ 60th Birthday | - |
dc.description.abstract | Epoxy and aziridinyl enolsilanes react as dienophiles in intramolecular (4+3) cycloadditions with typically challenging dienes such as pyrroles, thiophenes and benzenes. They also react as enophiles in intramolecular (3+2) reactions with dienes and alkenes. The reactions proceed through activated epoxides and aziridines as intermediates and therefore the cycloadducts can be obtained with high ee. | - |
dc.language | eng | - |
dc.relation.ispartof | 102nd Canadian Chemistry Conference and Exhibition | - |
dc.title | Applications of Epoxy and Aziridinyl Enolsilanes in Intramolecular (4+3) and (3+2) Cycloadditions | - |
dc.type | Conference_Paper | - |
dc.identifier.email | Chiu, P: pchiu@hku.hk | - |
dc.identifier.authority | Chiu, P=rp00680 | - |
dc.identifier.hkuros | 305409 | - |