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- Publisher Website: 10.1002/anie.201703300
- Scopus: eid_2-s2.0-85020398937
- PMID: 28500664
- WOS: WOS:000403017000018
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Article: Ligand-Promoted Rhodium(III)-Catalyzed ortho-C−H Amination with Free Amines
| Title | Ligand-Promoted Rhodium(III)-Catalyzed ortho-C−H Amination with Free Amines |
|---|---|
| Authors | |
| Keywords | amines amination rhodium quinolines ligand design |
| Issue Date | 2017 |
| Citation | Angewandte Chemie - International Edition, 2017, v. 56, n. 26, p. 7449-7453 How to Cite? |
| Abstract | © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Ligand development for rhodium(III)-catalyzed C−H activation reactions has largely been limited to cyclopentadienyl (Cp) based scaffolds. 2-Methylquinoline has now been identified as a feasible ligand that can coordinate to the metal center of Cp*RhCl to accelerate the cleavage of the C−H bond of N-pentafluorophenylbenzamides, providing a new structural lead for ligand design. The compatibility of this reaction with secondary free amines and anilines also overcomes the limitations of palladium(II)-catalyzed C−H amination reactions. |
| Persistent Identifier | http://hdl.handle.net/10722/277077 |
| ISSN | 2021 Impact Factor: 16.823 2020 SCImago Journal Rankings: 5.831 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Wang, Huai Wei | - |
| dc.contributor.author | Lu, Yi | - |
| dc.contributor.author | Zhang, Bing | - |
| dc.contributor.author | He, Jian | - |
| dc.contributor.author | Xu, Hua Jin | - |
| dc.contributor.author | Kang, Yan Shang | - |
| dc.contributor.author | Sun, Wei Yin | - |
| dc.contributor.author | Yu, Jin Quan | - |
| dc.date.accessioned | 2019-09-18T08:35:32Z | - |
| dc.date.available | 2019-09-18T08:35:32Z | - |
| dc.date.issued | 2017 | - |
| dc.identifier.citation | Angewandte Chemie - International Edition, 2017, v. 56, n. 26, p. 7449-7453 | - |
| dc.identifier.issn | 1433-7851 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/277077 | - |
| dc.description.abstract | © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Ligand development for rhodium(III)-catalyzed C−H activation reactions has largely been limited to cyclopentadienyl (Cp) based scaffolds. 2-Methylquinoline has now been identified as a feasible ligand that can coordinate to the metal center of Cp*RhCl to accelerate the cleavage of the C−H bond of N-pentafluorophenylbenzamides, providing a new structural lead for ligand design. The compatibility of this reaction with secondary free amines and anilines also overcomes the limitations of palladium(II)-catalyzed C−H amination reactions. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Angewandte Chemie - International Edition | - |
| dc.subject | amines | - |
| dc.subject | amination | - |
| dc.subject | rhodium | - |
| dc.subject | quinolines | - |
| dc.subject | ligand design | - |
| dc.title | Ligand-Promoted Rhodium(III)-Catalyzed ortho-C−H Amination with Free Amines | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/anie.201703300 | - |
| dc.identifier.pmid | 28500664 | - |
| dc.identifier.scopus | eid_2-s2.0-85020398937 | - |
| dc.identifier.volume | 56 | - |
| dc.identifier.issue | 26 | - |
| dc.identifier.spage | 7449 | - |
| dc.identifier.epage | 7453 | - |
| dc.identifier.eissn | 1521-3773 | - |
| dc.identifier.isi | WOS:000403017000018 | - |
| dc.identifier.issnl | 1433-7851 | - |