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Article: Spontaneous Self-Assembly of a Mono-Component Polyimide Bearing Terminal Hydrogen-Bonding Sites in a Single Solvent

TitleSpontaneous Self-Assembly of a Mono-Component Polyimide Bearing Terminal Hydrogen-Bonding Sites in a Single Solvent
Authors
KeywordsSelf assembly
Porous nanoparticles
Polyimides
Hydrogen bonding
Issue Date2009
Citation
Macromolecular Rapid Communications, 2009, v. 30, n. 11, p. 892-896 How to Cite?
AbstractA unique example of macromolecular self-assembly, where a mono-component homopolyimide bearing carboxy end-groups spontaneously forms nanopartilces with novel dimple-like morphology in a single good solvent, is presented. The self-assembly process is dramatically affected by the solution concentration and the temperature. It is proposed that such an unexpected self-assembly behavior is a synergistic result of the selfcomplementary hydrogen bonding between carboxy end-groups and the propensity to parallel packing of polyimide chains through aromatic interactions. © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Persistent Identifierhttp://hdl.handle.net/10722/276840
ISSN
2023 Impact Factor: 4.2
2023 SCImago Journal Rankings: 1.056
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLiu, Xikui-
dc.contributor.authorLiu, Junzhi-
dc.contributor.authorJiang, Ming-
dc.date.accessioned2019-09-18T08:34:49Z-
dc.date.available2019-09-18T08:34:49Z-
dc.date.issued2009-
dc.identifier.citationMacromolecular Rapid Communications, 2009, v. 30, n. 11, p. 892-896-
dc.identifier.issn1022-1336-
dc.identifier.urihttp://hdl.handle.net/10722/276840-
dc.description.abstractA unique example of macromolecular self-assembly, where a mono-component homopolyimide bearing carboxy end-groups spontaneously forms nanopartilces with novel dimple-like morphology in a single good solvent, is presented. The self-assembly process is dramatically affected by the solution concentration and the temperature. It is proposed that such an unexpected self-assembly behavior is a synergistic result of the selfcomplementary hydrogen bonding between carboxy end-groups and the propensity to parallel packing of polyimide chains through aromatic interactions. © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.-
dc.languageeng-
dc.relation.ispartofMacromolecular Rapid Communications-
dc.subjectSelf assembly-
dc.subjectPorous nanoparticles-
dc.subjectPolyimides-
dc.subjectHydrogen bonding-
dc.titleSpontaneous Self-Assembly of a Mono-Component Polyimide Bearing Terminal Hydrogen-Bonding Sites in a Single Solvent-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/marc.200800773-
dc.identifier.scopuseid_2-s2.0-66749177215-
dc.identifier.volume30-
dc.identifier.issue11-
dc.identifier.spage892-
dc.identifier.epage896-
dc.identifier.eissn1521-3927-
dc.identifier.isiWOS:000266963800002-
dc.identifier.issnl1022-1336-

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