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Article: Ligand-Enabled Pd(II)-Catalyzed Bromination and Iodination of C(sp3)-H Bonds

TitleLigand-Enabled Pd(II)-Catalyzed Bromination and Iodination of C(sp3)-H Bonds
Authors
Issue Date2017
Citation
Journal of the American Chemical Society, 2017, v. 139, n. 16, p. 5724-5727 How to Cite?
Abstract© 2017 American Chemical Society. We herein report the palladium(II)-catalyzed bromination and iodination of a variety of α-hydrogen-containing carboxylic acid and amino acid-derived amides. These reactions are exclusively enabled by quinoline-type ligands. The halogenated products obtained in this reaction are highly versatile and rapidly undergo further diversification. Further, we report the first example of a free carboxylic acid-directed Pd(II)-catalyzed C(sp3)-H bromination, enabled by quinoline ligands.
Persistent Identifierhttp://hdl.handle.net/10722/276513
ISSN
2023 Impact Factor: 14.4
2023 SCImago Journal Rankings: 5.489
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorZhu, Ru Yi-
dc.contributor.authorSaint-Denis, Tyler G.-
dc.contributor.authorShao, Ying-
dc.contributor.authorHe, Jian-
dc.contributor.authorSieber, Joshua D.-
dc.contributor.authorSenanayake, Chris H.-
dc.contributor.authorYu, Jin Quan-
dc.date.accessioned2019-09-18T08:33:50Z-
dc.date.available2019-09-18T08:33:50Z-
dc.date.issued2017-
dc.identifier.citationJournal of the American Chemical Society, 2017, v. 139, n. 16, p. 5724-5727-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/276513-
dc.description.abstract© 2017 American Chemical Society. We herein report the palladium(II)-catalyzed bromination and iodination of a variety of α-hydrogen-containing carboxylic acid and amino acid-derived amides. These reactions are exclusively enabled by quinoline-type ligands. The halogenated products obtained in this reaction are highly versatile and rapidly undergo further diversification. Further, we report the first example of a free carboxylic acid-directed Pd(II)-catalyzed C(sp3)-H bromination, enabled by quinoline ligands.-
dc.languageeng-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titleLigand-Enabled Pd(II)-Catalyzed Bromination and Iodination of C(sp3)-H Bonds-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/jacs.7b02196-
dc.identifier.pmid28391681-
dc.identifier.scopuseid_2-s2.0-85018290222-
dc.identifier.volume139-
dc.identifier.issue16-
dc.identifier.spage5724-
dc.identifier.epage5727-
dc.identifier.eissn1520-5126-
dc.identifier.isiWOS:000400321500023-
dc.identifier.issnl0002-7863-

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