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Article: Ligand-Promoted Borylation of C(sp3)-H Bonds with Palladium(II) Catalysts

TitleLigand-Promoted Borylation of C(sp3)-H Bonds with Palladium(II) Catalysts
Authors
KeywordsC-H activation
amino acids
borylation
palladium
synthetic methods
Issue Date2016
Citation
Angewandte Chemie - International Edition, 2016, v. 55, n. 2, p. 785-789 How to Cite?
Abstract© 2016 Wiley-VCH Verlag GmbH & Co. KGaA. A quinoline-based ligand effectively promotes the palladium-catalyzed borylation of C(sp3)-H bonds. Primary β-C(sp3)-H bonds in carboxylic acid derivatives as well as secondary C(sp3)-H bonds in a variety of carbocyclic rings, including cyclopropanes, cyclobutanes, cyclopentanes, cyclohexanes, and cycloheptanes, can thus be borylated. This directed borylation method complements existing iridium(I)- and rhodium(I)-catalyzed C-H borylation reactions in terms of scope and operational conditions.
Persistent Identifierhttp://hdl.handle.net/10722/276502
ISSN
2023 Impact Factor: 16.1
2023 SCImago Journal Rankings: 5.300
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorHe, Jian-
dc.contributor.authorJiang, Heng-
dc.contributor.authorTakise, Ryosuke-
dc.contributor.authorZhu, Ru Yi-
dc.contributor.authorChen, Gang-
dc.contributor.authorDai, Hui Xiong-
dc.contributor.authorDhar, T. G.Murali-
dc.contributor.authorShi, Jun-
dc.contributor.authorZhang, Hao-
dc.contributor.authorCheng, Peter T.W.-
dc.contributor.authorYu, Jin Quan-
dc.date.accessioned2019-09-18T08:33:48Z-
dc.date.available2019-09-18T08:33:48Z-
dc.date.issued2016-
dc.identifier.citationAngewandte Chemie - International Edition, 2016, v. 55, n. 2, p. 785-789-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/276502-
dc.description.abstract© 2016 Wiley-VCH Verlag GmbH & Co. KGaA. A quinoline-based ligand effectively promotes the palladium-catalyzed borylation of C(sp3)-H bonds. Primary β-C(sp3)-H bonds in carboxylic acid derivatives as well as secondary C(sp3)-H bonds in a variety of carbocyclic rings, including cyclopropanes, cyclobutanes, cyclopentanes, cyclohexanes, and cycloheptanes, can thus be borylated. This directed borylation method complements existing iridium(I)- and rhodium(I)-catalyzed C-H borylation reactions in terms of scope and operational conditions.-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie - International Edition-
dc.subjectC-H activation-
dc.subjectamino acids-
dc.subjectborylation-
dc.subjectpalladium-
dc.subjectsynthetic methods-
dc.titleLigand-Promoted Borylation of C(sp3)-H Bonds with Palladium(II) Catalysts-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.201509996-
dc.identifier.pmid26611496-
dc.identifier.scopuseid_2-s2.0-84956827984-
dc.identifier.volume55-
dc.identifier.issue2-
dc.identifier.spage785-
dc.identifier.epage789-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:000368069200061-
dc.identifier.issnl1433-7851-

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