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- Publisher Website: 10.3762/bjoc.15.177
- Scopus: eid_2-s2.0-85070318220
- PMID: 31467603
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Article: Synthesis of a [6]rotaxane with singly threaded γ-cyclodextrins as a single stereoisomer
| Title | Synthesis of a [6]rotaxane with singly threaded γ-cyclodextrins as a single stereoisomer |
|---|---|
| Authors | |
| Keywords | cucurbit[6]uril cyclodextrin macrocycles mechanostereoisomer rotaxane |
| Issue Date | 2019 |
| Publisher | Beilstein-Institut. The Journal's web site is located at http://www.beilstein-journals.org/bjoc/home/home.htm |
| Citation | Beilstein Journal of Organic Chemistry, 2019, v. 15, p. 1829-1837 How to Cite? |
| Abstract | A series of hetero [4]-, [5]- and [6]rotaxanes containing both cucurbit[6]uril (CB[6]) and γ-cyclodextrin (γ-CD) as the macrocyclic components have been synthesized via a threading-followed-by-stoppering approach. Due to the orthogonal binding of CB[6] to ammonium and γ-CD to biphenylene/tetra(ethylene glycol), the [n]rotaxanes display a specific sequence of the interlocked macrocycles. In addition, despite of the asymmetry of γ-CD with respect to the orthogonal plane of the axle, only one stereoisomer of the [6]rotaxane was obtained. |
| Persistent Identifier | http://hdl.handle.net/10722/274834 |
| ISSN | 2023 Impact Factor: 2.2 2023 SCImago Journal Rankings: 0.517 |
| PubMed Central ID | |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | MAN, JYH | - |
| dc.contributor.author | Au-Yeung, HY | - |
| dc.date.accessioned | 2019-09-10T02:29:48Z | - |
| dc.date.available | 2019-09-10T02:29:48Z | - |
| dc.date.issued | 2019 | - |
| dc.identifier.citation | Beilstein Journal of Organic Chemistry, 2019, v. 15, p. 1829-1837 | - |
| dc.identifier.issn | 1860-5397 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/274834 | - |
| dc.description.abstract | A series of hetero [4]-, [5]- and [6]rotaxanes containing both cucurbit[6]uril (CB[6]) and γ-cyclodextrin (γ-CD) as the macrocyclic components have been synthesized via a threading-followed-by-stoppering approach. Due to the orthogonal binding of CB[6] to ammonium and γ-CD to biphenylene/tetra(ethylene glycol), the [n]rotaxanes display a specific sequence of the interlocked macrocycles. In addition, despite of the asymmetry of γ-CD with respect to the orthogonal plane of the axle, only one stereoisomer of the [6]rotaxane was obtained. | - |
| dc.language | eng | - |
| dc.publisher | Beilstein-Institut. The Journal's web site is located at http://www.beilstein-journals.org/bjoc/home/home.htm | - |
| dc.relation.ispartof | Beilstein Journal of Organic Chemistry | - |
| dc.rights | This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License. | - |
| dc.subject | cucurbit[6]uril | - |
| dc.subject | cyclodextrin | - |
| dc.subject | macrocycles | - |
| dc.subject | mechanostereoisomer | - |
| dc.subject | rotaxane | - |
| dc.title | Synthesis of a [6]rotaxane with singly threaded γ-cyclodextrins as a single stereoisomer | - |
| dc.type | Article | - |
| dc.identifier.email | Au-Yeung, HY: hoyuay@hku.hk | - |
| dc.identifier.authority | Au-Yeung, HY=rp01819 | - |
| dc.description.nature | published_or_final_version | - |
| dc.identifier.doi | 10.3762/bjoc.15.177 | - |
| dc.identifier.pmid | 31467603 | - |
| dc.identifier.pmcid | PMC6693375 | - |
| dc.identifier.scopus | eid_2-s2.0-85070318220 | - |
| dc.identifier.hkuros | 305038 | - |
| dc.identifier.volume | 15 | - |
| dc.identifier.spage | 1829 | - |
| dc.identifier.epage | 1837 | - |
| dc.identifier.isi | WOS:000480423800001 | - |
| dc.publisher.place | Germany | - |
| dc.identifier.issnl | 1860-5397 | - |