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- Publisher Website: 10.1002/anie.201806272
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Article: Photochromic Benzo[b]phosphole Alkynylgold(I) Complexes with Mechanochromic Property to Serve as Multistimuli-Responsive Materials
Title | Photochromic Benzo[b]phosphole Alkynylgold(I) Complexes with Mechanochromic Property to Serve as Multistimuli-Responsive Materials |
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Authors | |
Keywords | benzo[b]phosphole gold mechanochromism multistimuli-responsive materials photochromism |
Issue Date | 2019 |
Publisher | Wiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home |
Citation | Angewandte Chemie (International Edition), 2019, v. 58 n. 10, p. 3027-3031 How to Cite? |
Abstract | A series of novel benzo[b]phosphole alkynylgold(I) complexes has been demonstrated to display photochromic and mechanochromic properties upon applying the respective stimuli of light and mechanical force. Promising multistimuliresponsive properties of this series of gold(I) complexes have been successfully achieved through judicious molecular design, which involves incorporation of the photochromic dithienylethene- containing benzo[b]phosphole into the triphenylaminecontaining arylethynyl ligand that is susceptible to mechanical force-induced color changes via gold(I) complexation. With excellent thermal irreversibility and robust fatigue resistance of this series of gold(I) complexes, multicolor states controlled by the photochromism and mechanochromism have been realized. Repeatable photochromic and mechanochromic cycles without apparent loss of reactivity have also been observed under ambient conditions. The present work provides important insight and an alternative strategy for the molecular design of multistimuli-responsive materials, paving the way for further development of the underexplored photoresponsive gold(I) complexes and the multistate photocontrolled system. |
Persistent Identifier | http://hdl.handle.net/10722/269574 |
ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | WU, MW | - |
dc.contributor.author | Ng, M | - |
dc.contributor.author | Yam, VWW | - |
dc.date.accessioned | 2019-04-24T08:10:27Z | - |
dc.date.available | 2019-04-24T08:10:27Z | - |
dc.date.issued | 2019 | - |
dc.identifier.citation | Angewandte Chemie (International Edition), 2019, v. 58 n. 10, p. 3027-3031 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10722/269574 | - |
dc.description.abstract | A series of novel benzo[b]phosphole alkynylgold(I) complexes has been demonstrated to display photochromic and mechanochromic properties upon applying the respective stimuli of light and mechanical force. Promising multistimuliresponsive properties of this series of gold(I) complexes have been successfully achieved through judicious molecular design, which involves incorporation of the photochromic dithienylethene- containing benzo[b]phosphole into the triphenylaminecontaining arylethynyl ligand that is susceptible to mechanical force-induced color changes via gold(I) complexation. With excellent thermal irreversibility and robust fatigue resistance of this series of gold(I) complexes, multicolor states controlled by the photochromism and mechanochromism have been realized. Repeatable photochromic and mechanochromic cycles without apparent loss of reactivity have also been observed under ambient conditions. The present work provides important insight and an alternative strategy for the molecular design of multistimuli-responsive materials, paving the way for further development of the underexplored photoresponsive gold(I) complexes and the multistate photocontrolled system. | - |
dc.language | eng | - |
dc.publisher | Wiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home | - |
dc.relation.ispartof | Angewandte Chemie (International Edition) | - |
dc.subject | benzo[b]phosphole | - |
dc.subject | gold | - |
dc.subject | mechanochromism | - |
dc.subject | multistimuli-responsive materials | - |
dc.subject | photochromism | - |
dc.title | Photochromic Benzo[b]phosphole Alkynylgold(I) Complexes with Mechanochromic Property to Serve as Multistimuli-Responsive Materials | - |
dc.type | Article | - |
dc.identifier.email | Ng, M: mkyng@hku.hk | - |
dc.identifier.email | Yam, VWW: wwyam@hku.hk | - |
dc.identifier.authority | Yam, VWW=rp00822 | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1002/anie.201806272 | - |
dc.identifier.scopus | eid_2-s2.0-85052498444 | - |
dc.identifier.hkuros | 297348 | - |
dc.identifier.hkuros | 312994 | - |
dc.identifier.volume | 58 | - |
dc.identifier.spage | 3027 | - |
dc.identifier.epage | 3031 | - |
dc.identifier.isi | WOS:000459709300009 | - |
dc.publisher.place | Germany | - |
dc.identifier.issnl | 1433-7851 | - |